Characterisation of defects in porous silicon as an anode material using positron annihilation Doppler Broadening Spectroscopy

Here we present Positron Annihilation Doppler Broadening Spectroscopy (PADBS) as a powerful method to analyse the origin and development of defect processes in porous silicon structures as a result of alloying with lithium for the use in battery anode applications. Several prepared anodes were lithiated (discharged against Li⁺/Li)...

Scanning Probe Microscopy Facility for Operando Study of Redox Processes on Lithium ion Battery Electrodes

An Atomic Force Microscope (AFM) is combined with a special designed glovebox system and coupled to a Galvanostat/Potentiostat to allow measurements on electrochemical properties for battery research. An open cell design with electrical contacts makes it possible to reach the electrode surface with the cantilever so as to perform measurements...

Localised Corrosion Studies on FSW Al-Li alloys: Microstructure Effect

Al-Li alloys were introduced for the use in aerospace applications due to its many advantages over steel such as its low density, good thermal and electrical conductivity and corrosion resistance of these alloys. The current generation of Al-Li alloys were developed to replace the currently used AA2024 alloy in commercial airframes, military and...

The residual stress characteristics and mechanical behavior of shot peened fiber metal laminates based on the aluminium-lithium alloy

The effect of shot peen forming on the mechanical behavior of fiber metal laminates (FMLs) based on aluminium-lithium alloy was investigated to reveal the strengthening mechanism and to dispel the suspicion that shot peen forming may result in the performance deterioration of FMLs. The interlaminar, static strength and fatigue properties of...

Damage tolerance property comparisons for 2000 and 8000 series aluminium plate alloys

This report compares the mechanical properties, fracture toughness and fatigue crack growth properties of the damage tolerant/medium strength aluminium plate alloys 2024-T351, 2324-T39, 8090-T651 and 8090-T8171. The main objective, in view of previous work, was to determine whether damage tolerant 8090-T8171 plate can advantageously replace the...

Influence of gust spectrum variations on fatigue crack growth behaviour of damage tolerant aluminium-lithium sheet materials

Flight simulation fatigue growth tests were done on 1.6 mm thick sheets of the damage tolerant aluminium-lithium (Al-Li) alloys 2091-T84 and 8090-T81 in comparison with the industry standard conventional damage tolerant alloy 2024-T3. The flight simulation load spectrum, the gust spectrum MINITWIST, was used in four versions: untruncated,...

Stress corrosion resistance of damage tolerant aluminium-lithium sheet materials

The SCC resistances of three damage tolerant aluminium sheet materials were determined by means of the ASCOR (Automated Stress COrrosion Ring) test. The conventional damage tolerant sheet material 2024-T3 was used as reference. The SCC resistance of 8090-T81 turned out to be only slightly lower than the SCC resistance of 2024-T3. In contrast,...

Outdoor corrosion testing of aluminium-lithium alloys

Outdoor corrosion and stress corrosion tests were conducted on Al-Li plate and sheet materials for 3 and almost 5 years respectively. The results can be summarized as follows: Corrosion: Peak aged XXXA-T651 (8090-T651) exhibited greater exfoliation corrosion resistance than 2024-T351 and 2324-T39 plate. 2091-T3 and 2024-T3 sheet were found to be...