Superconducting Contacts for Atomically Precise Graphene Nanoribbons

This dissertation centers around two topics: graphene nanoribbons (GNRs) and superconductors. The aim of this thesis is to work towards combine these two topics, in order to study how superconducting correlations interact with magnetic correlations within graphene nanoribbons, such as the magnetic edge states present in the zigzag edges of...

MoRe Electrodes with 10 nm Nanogaps for Electrical Contact to Atomically Precise Graphene Nanoribbons

Atomically precise graphene nanoribbons (GNRs) are predicted to exhibit exceptional edge-related properties, such as localized edge states, spin polarization, and half-metallicity. However, the absence of low-resistance nanoscale electrical contacts to the GNRs hinders harnessing their properties in field-effect transistors. In this paper, we...

Titanium Trisulfide Nanosheets and Nanoribbons for Field Emission-Based Nanodevices

The field emission (FE) properties of TiS3 nanosheets and nanoribbons, synthesized by direct sulfuration of bulk titanium, are investigated. The nanosheets show an enhanced FE behavior with a low turn-on field of ∼0.3 V/μm, required for drawing an emission current density of ∼10 μA/cm2. Interestingly, the TiS3 nanosheet emitter delivered a...

Optimized graphene electrodes for contacting graphene nanoribbons

Atomically precise graphene nanoribbons (GNRs) are a promising emerging class of designer quantum materials with electronic properties that are tunable by chemical design. However, many challenges remain in the device integration of these materials, especially regarding contacting strategies. We report on the device integration of uniaxially...

Graphene Nanoribbons based 5-bit Digital-to-Analog Converter

McCulloch-Pitts neuron structures are comprised of a number of synaptic inputs and a decision element, called soma. In this paper, we propose a 5-bit Graphene Nanoribbon (GNR)-based DAC to fulfill the role of the summation element featuring programmable input weights. The proposed GNR-based 5-bit DAC relies on: (i) GNR unit current cells and ...

Graphene-Based Computing: Nanoribbon Logic Gates & Circuits

As CMOS feature size is reaching atomic dimensions, unjustifiable static power, reliability, and economic implications are exacerbating, thus prompting for research on new materials, devices, and/or computation paradigms. Within this context, Graphene Nanoribbons (GNRs), owing to graphene’s excellent electronic properties, may serve as basic...

Controlled Quantum Dot Formation in Atomically Engineered Graphene Nanoribbon Field-Effect Transistors

Graphene nanoribbons (GNRs) have attracted strong interest from researchers worldwide, as they constitute an emerging class of quantum-designed materials. The major challenges toward their exploitation in electronic applications include reliable contacting, complicated by their small size (<50 nm), and the preservation of their physical...

DNA sensing with nanopores in graphene nanoribbons

The information that can be extracted from DNA base sequences, is important for our understanding of biology, for insights in disease, and the way we practice medicine. The technology that one uses to determine DNA-base sequences is called ‘DNA sequencing’. A portable device that enables fast and accurate sequencing, can potentially greatly...

Probing DNA Translocations with Inplane Current Signals in a Graphene Nanoribbon with a Nanopore

Many theoretical studies predict that DNA sequencing should be feasible by monitoring the transverse current through a graphene nanoribbon while a DNA molecule translocates through a nanopore in that ribbon. Such a readout would benefit from the special transport properties of graphene, provide ultimate spatial resolution because of the single...

On Effective Graphene Based Computing

With CMOS feature size heading towards atomic dimensions, unjustifiable static power, reliability, and economic implications are exacerbating, prompting for research on new materials, devices, and/or computation paradigms. Within this context, Graphene Nanoribbons (GNRs), owing to graphene's excellent electronic properties, may serve as basic...

Electronic Transport in Helium Beam Modified Graphene and Ballistic Josephson Junctions

This thesis describes the capabilities of the helium ion microscope (HIM) and that of graphene to explore fundamental physics and novel applications. While graphene offers superior electronic properties, the helium ion microscope allows us to combine imaging and modification of materials at the nanoscale. We used the capabilities of HIM to grow...

In-situ Transmission Electron Microscopy Studies on Graphene

Electronic transport in helium-ion-beam etched encapsulated graphene nanoribbons

We report the etching of and electronic transport in nanoribbons of graphene sandwiched between atomically flat hexagonal boron nitride (h-BN). The etching of ribbons of varying width was achieved with a focused beam of 30 keV He⁺ ions. Using in-situ electrical measurements, we established a critical dose of 7000 ions nm<sup>−2<...

Photodetection with novel materials: Colloidal quantum dots nanoribbons and layered materials

Models and Simulations of Carrier Transport in Novel Nanoelectronic Devices

Nanotechnology is the field of applied science and technology that aims to manipulate, test and produce devices and systems which have dimensions comparable to the atomic and molecular scale, that is few tens of nanometers and smaller. Amongst the wide range of fields touched by nanotechnology, nanoelectronics is quite a peculiar one. In fact...