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Aghaeian, S. (author), Norouzi, F. (author), Sloof, W.G. (author), Mol, J.M.C. (author), Bottger, A.J. (author)The parabolic growth rate constant (k<sub>p</sub>) of high-temperature oxidation of steels is predicted via a data analytics approach. Four machine learning models including Artificial Neural Networks, Random Forest, k-Nearest Neighbors, and Support Vector Regression are trained to establish the relations between the input features ...journal article 2023
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Belloni, C. (author), Korving, L. (author), Witkamp, G.J. (author), Brück, E.H. (author), Dugulan, A.I. (author)Phosphorus (P) removal from freshwater bodies to ultra-low concentrations is fundamental to prevent eutrophication, while its recovery is necessary to close the P usage cycle. Iron oxide-based adsorbents seem promising candidates, being abundant, cheap, and easy to synthesize compounds, with good affinity for P. Affinity is the key parameter...journal article 2023
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Aghaeian, S. (author), Brouwer, J.C. (author), Sloof, W.G. (author), Mol, J.M.C. (author), Bottger, A.J. (author)Since the oxidation reactions in the process of steel production occur in harsh conditions (i.e., high temperatures and gas atmospheres), it is practically impossible to observe in situ the compositional changes in the steel and the formed oxide scale. Hence, a coupled thermodynamic-kinetic numerical model is developed that predicts the...journal article 2023
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Zhao, Guofeng (author), Moulijn, J.A. (author), Kapteijn, F. (author), Dautzenberg, Frits M. (author), Xu, Bin (author), Lu, Yong (author)Heterogeneous catalysis plays a pivotal role in the current chemical and energy vectors production. Notably, to fully utilize the intrinsic activity and selectivity of a catalyst, the chemical reactor has to be designed and operated optimally to achieve enhanced heat/mass transfer, well-defined contact time of reactants, uniform flow pattern,...journal article 2023
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Belloni, C. (author), Korving, L. (author), Witkamp, G. J. (author), Brück, E.H. (author), de Jager, P. (author), Dugulan, A.I. (author)Hybrid anion exchange adsorbents (HAIX) seem promising to prevent eutrophication and recover phosphate (P). HAIX consist of an anion exchange resin (AIX) backbone, promoting anion physisorption (outer-sphere complex), impregnated with iron (hydr)oxide nanoparticles (NPs), for selective P chemisorption (inner-sphere complex). In this work, for...journal article 2023
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Rashid, Roomina (author), Abdinejad, M. (author), Motlagh, Mozhgan Khorasani (author), Noroozifar, Meissam (author), Kraatz, Heinz Bernhard (author)Electrochemical reduction of carbon dioxide (CO<sub>2</sub>RR) product distribution has been found to be dependent on several key factors, such as catalyst surface morphology, stability, and porosity. Metal-modified carbon-based materials have received a lot of attention in CO<sub>2</sub>RR. However, designing a highly active metal carbon...journal article 2023
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Hu, L. (author), Pinto, D. (author), Urakawa, A. (author)Direct valorization of methane via oxidative coupling of methane (OCM) is an encouraging alternative to conventional oil-based processes for the production of light hydrocarbons (ethane and ethylene). Abundant, inexpensive simple oxides such as MgO and La<sub>2</sub>O<sub>3</sub> possess the ability to selectively activate methane. However,...journal article 2023
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van Veldhuizen, B.N. (author), Zera, E. (author), van Biert, L. (author), Modena, S. (author), Visser, K. (author), Aravind, P.V. (author)Solid Oxide Fuel Cell (SOFC) systems have the potential to reduce emissions from seagoing vessels. However, it is unknown whether ship motions influence the system's operation. In this research, a 1.5 kW SOFC module is operated on an inclination platform that emulates ship motions, to evaluate the influence of static and dynamic inclinations...journal article 2023
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Klein, Julian (author), Kampermann, Laura (author), Mockenhaupt, B.M. (author), Behrens, Malte (author), Strunk, Jennifer (author), Bacher, Gerd (author)The Tauc plot is a method originally developed to derive the optical gap of amorphous semiconductors such as amorphous germanium or silicon. By measuring the absorption coefficient α(hν) and plotting (Formula presented.) versus photon energy hν, a value for the optical gap (Tauc gap) is determined. In this way non-direct optical transitions...journal article 2023
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Buisma-Yi, S.C. (author), Heijbroek, A.C. (author), Cutz, L. (author), Pillay, S. (author), de Jong, W. (author), Abeel, T.E.P.M.F. (author), Gebert, J. (author)Application of biochar to landfill cover soils can purportedly improve methane (CH4) oxidation rates, but understanding the combined effects of soil texture, compaction, and biochar on the activity and composition of the methanotrophs is limited. The amendment of wood biochar on two differently textured landfill cover soils at three compaction...journal article 2023
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Pagani, Stefania (author), Salerno, Manuela (author), Filardo, Giuseppe (author), Locs, Janis (author), van Osch, G.J.V.M. (author), Vecstaudza, Jana (author), Dolcini, Laura (author), Borsari, Veronica (author), Fini, Milena (author), Giavaresi, Gianluca (author), Columbaro, Marta (author)Osteochondral lesions, when not properly treated, may evolve into osteoarthritis (OA), especially in the elderly population, where altered joint function and quality are usual. To date, a collagen/collagen–magnesium–hydroxyapatite (Col/Col-Mg-HAp) scaffold (OC) has demonstrated good clinical results, although suboptimal subchondral bone...journal article 2023
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Adwani, Dheeraj (author), Sreeram, Anand (author), Pipintakos, Georgios (author), Mirwald, Johannes (author), Wang, Yudi (author), Hajj, Ramez (author), Jing, R. (author), Bhasin, Amit (author)The design and use of antioxidant additives to reduce or slow down the aging of asphalt binders can bring about tremendous benefits to the asphalt industry. Despite many isolated and scattered research efforts showing mixed results, the application of this science to engineering-based solutions has been limited due to variability in results and...journal article 2023
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Zhang, Hao (author), Bolshakov, Aleksei (author), Meena, Raghavendra (author), Garcia, Gustavo A. (author), Dugulan, A.I. (author), Parastaev, Alexander (author), Li, Guanna (author), Hensen, Emiel J.M. (author), Kosinov, Nikolay (author)Non-oxidative coupling of methane is a promising route to obtain ethylene directly from natural gas. We synthesized siliceous [Fe]zeolites with MFI and CHA topologies and found that they display high selectivity (>90 % for MFI and >99 % for CHA) to ethylene and ethane among gas-phase products. Deactivated [Fe]zeolites can be regenerated...journal article 2023
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Yao, Z. (author), Yang, G. (author), Han, C. (author), Procel Moya, P.A. (author), Özkol, E. (author), Yan, J. (author), Zhao, Y. (author), Cao, L. (author), van Swaaij, R.A.C.M.M. (author), Mazzarella, L. (author), Isabella, O. (author)Passivating contacts are crucial for realizing high-performance crystalline silicon solar cells. Herein, contact formation by plasma-enhanced chemical vapor deposition (PECVD) followed by an annealing step is focused on. Poly-SiO<sub>x</sub> passivating contacts by combining plasma-assisted N<sub>2</sub>O-based oxidation of silicon (PANO-SiO...journal article 2023
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Piergentili, I. (author), Cai, Mao (author), Klemm, B. (author), Xu, B. (author), Luo, Sanzhong (author), Eelkema, R. (author)The redox balance in tumor and diseased cells often leads to the production of reactive oxygen species (ROS). Many ROS-responsive materials based on sulfur oxidation have been reported with the goal of achieving controlled delivery at the tumor. However, these materials often lack responsiveness to low ROS concentrations present in the tumor...journal article 2023
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Templated Synthesis of Diamond Nanopillar Arrays Using Porous Anodic Aluminium Oxide (AAO) MembranesZhang, C. (author), Liu, Z. (author), Li, Chun (author), Buijnsters, J.G. (author)Diamond nanostructures are mostly produced from bulk diamond (single- or polycrystalline) by using time-consuming and/or costly subtractive manufacturing methods. In this study, we report the bottom-up synthesis of ordered diamond nanopillar arrays by using porous anodic aluminium oxide (AAO). Commercial ultrathin AAO membranes were adopted as...journal article 2023
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Inamdar, A.S. (author), van Soestbergen, Michiel (author), Mavinkurve, Amar (author), van Driel, W.D. (author), Zhang, Kouchi (author)Moulding compounds used for encapsulating electronics typically occupy a large portion of package volume and are most exposed to the external environment. Under harsh conditions such as high temperature, humidity, and mechanical vibrations, constituent materials of electronic components degrade, resulting in a change in their thermal, mechanical...conference paper 2023
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Basyooni, Mohamed A. (author), En-nadir, Redouane (author), Rahmani, Khalid (author), Eker, Yasin Ramazan (author)In this study, we delved into the influence of Ir nanofilm coating thickness on the optical and optoelectronic behavior of ultrathin MoO3 wafer-scale devices. Notably, the 4 nm Ir coating showed a negative Hall voltage and high carrier concentration of 1.524 × 1019 cm−3 with 0.19 nm roughness. Using the Kubelka–Munk model, we found that the...journal article 2023
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Basyooni, Mohamed A. (author), Zaki, Shrouk E. (author), Rahmani, Khalid (author), En-nadir, Redouane (author), Eker, Yasin Ramazan (author)Surface plasmon technology is regarded as having significant potential for the enhancement of the performance of 2D oxide semiconductors, especially in terms of improving the light absorption of 2D MoO3 photodetectors. An ultrathin MoO3/Ir/SiO2/Si heterojunction Schottky self-powered photodetector is introduced here to showcase positive...journal article 2023
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Alali, Arkan (author), Hosseini-Abari, Afrouzossadat (author), Bahrami, A. (author), Yazdan Mehr, M. (author)Modification of paint with nanoparticles (NPs) provides self-cleaning, water/dirt-repellent, and other properties. Therefore, the aim of the present study was to biosynthesize silver (Ag) and copper oxide (CuO) NPs and to prepare NP-modified paint. To this end, AgNPs and CuONPs were biosynthesized using Bacillus atrophaeus spores and commercial...journal article 2023