Context. The subsurface oceans of icy satellites are among the most compelling among the potentially habitable environments in our Solar System. The question of whether a liquid subsurface layer can be maintained over geological timescales depends on its chemical composition. The composition of icy satellites is linked to that of the circumplanetary disk (CPD) in which they form. The CPD accretes material from the surrounding circumstellar disk in the vicinity of the planet, however, the degree of chemical inheritance is unclear. Aims. We aim to investigate the composition of ices in chemically reset or inherited circumplanetary disks to inform interior modeling and the interpretation of in situ measurements of icy solar system satellites, with an emphasis on the Galilean moon system. Methods. We used the radiation-thermochemical code ProDiMo to produce circumplanetary disk models and then extract the ice composition from time-dependent chemistry, incorporating gas-phase and grain-surface reactions. Results. The initial sublimation of ices during accretion may result in a CO2 -rich ice composition due to efficient OH formation at high gas densities. In the case of a Jovian CPD, the sublimation of accreted ices results in a CO2 iceline between the present-day orbits of Ganymede and Callisto. Sublimated ammonia ice is destroyed by background radiation while drifting towards the CPD midplane. Liberated nitrogen becomes locked in N2 due to efficient self-shielding, leaving ices depleted of ammonia. A significant ammonia ice component remains only when ices are inherited from the circumstellar disk. Conclusions. The observed composition of the Galilean moons is consistent with the sublimation of ices during accretion onto the CPD. In this scenario, the Galilean moon ices are nitrogen-poor and CO2 on Callisto is endogenous and primordial. The ice composition is significantly altered after an initial reset of accreted circumstellar ice. The chemical history of the Galilean moons stands in contrast to the Saturnian system, where the composition of the moons corresponds more closely with the directly inherited circumstellar disk material.@en

Supersonic plumes of water vapour and icy particles have been observed by the Cassini spacecraft during several flybys over Enceladus. These plumes originate from the Tiger Stripes located in the South Polar Terrain (SPT), and indicate the presence of a subsurface ocean under the icy crust which is salty and contains complex organic molecules. Other characteristics of the plumes, such as the vent temperature, mass flow rate, velocity and mass fraction of icy particles can be used to determine the conditions in the channel, linking the subsurface ocean to the icy surface. In this paper, we developed a fluid dynamics model that accounts for nucleation, particle growth, wall accretion and sublimation. The channel behaves similarly to a converging–diverging nozzle, which forms supersonic plumes due to a pressure difference between the reservoir where the subsurface ocean is located and the exosphere. The geometry of the channel and its evolution with accretion of gas and sublimation of ice are studied to reproduce the characteristics of the plumes observed by Cassini. We first performed a parameter study on the channel geometry to determine how it influences the plumes’ velocity, solid fraction and exit temperature. Our results show that the size of the icy particles is primarily dependent on the length of the channel, indicating that large particles (∼75μm) must originate from within a kilometer below the surface, while smaller particles (∼3μm) can originate from only hundreds of meters below the surface. We further show that the velocity of the flow, exit temperature and nucleation depend directly on the exit-to-throat size ratio. We find that the channel geometry evolves within a few tens of hours until an equilibrium is reached, when considering the accretion of gas to the walls, or sublimation of ice from the walls. As the channel closes due to accretion, the flow becomes thinner, which in turn reduces accretion. After around 70 h, the accretion is sufficiently slowed such that the geometry does not evolve anymore. This equilibrium geometry produces higher Mach numbers and a larger particle size and solid fraction compared to the initial geometry.@en

Supersonic plumes of water vapour and icy particles have been observed by the Cassini spacecraft during several flybys over Enceladus. These plumes originate from the Tiger Stripes located in the South Polar Terrain (SPT), and indicate the presence of a subsurface ocean under the icy crust which is salty and contains complex organic molecules. Other characteristics of the plumes, such as the vent temperature, mass flow rate, velocity and mass fraction of icy particles can be used to determine the conditions in the channel, linking the subsurface ocean to the icy surface. In this paper, we developed a fluid dynamics model that accounts for nucleation, particle growth, wall accretion and sublimation. The channel behaves similarly to a converging–diverging nozzle, which forms supersonic plumes due to a pressure difference between the reservoir where the subsurface ocean is located and the exosphere. The geometry of the channel and its evolution with accretion of gas and sublimation of ice are studied to reproduce the characteristics of the plumes observed by Cassini. We first performed a parameter study on the channel geometry to determine how it influences the plumes’ velocity, solid fraction and exit temperature. Our results show that the size of the icy particles is primarily dependent on the length of the channel, indicating that large particles (∼75μm) must originate from within a kilometer below the surface, while smaller particles (∼3μm) can originate from only hundreds of meters below the surface. We further show that the velocity of the flow, exit temperature and nucleation depend directly on the exit-to-throat size ratio. We find that the channel geometry evolves within a few tens of hours until an equilibrium is reached, when considering the accretion of gas to the walls, or sublimation of ice from the walls. As the channel closes due to accretion, the flow becomes thinner, which in turn reduces accretion. After around 70 h, the accretion is sufficiently slowed such that the geometry does not evolve anymore. This equilibrium geometry produces higher Mach numbers and a larger particle size and solid fraction compared to the initial geometry.@en

Supersonic plumes of water vapour and icy particles have been observed by the Cassini spacecraft during several flybys over Enceladus. These plumes originate from the Tiger Stripes located in the South Polar Terrain (SPT), and indicate the presence of a subsurface ocean under the icy crust which is salty and contains complex organic molecules. Other characteristics of the plumes, such as the vent temperature, mass flow rate, velocity and mass fraction of icy particles can be used to determine the conditions in the channel, linking the subsurface ocean to the icy surface. In this paper, we developed a fluid dynamics model that accounts for nucleation, particle growth, wall accretion and sublimation. The channel behaves similarly to a converging–diverging nozzle, which forms supersonic plumes due to a pressure difference between the reservoir where the subsurface ocean is located and the exosphere. The geometry of the channel and its evolution with accretion of gas and sublimation of ice are studied to reproduce the characteristics of the plumes observed by Cassini. We first performed a parameter study on the channel geometry to determine how it influences the plumes’ velocity, solid fraction and exit temperature. Our results show that the size of the icy particles is primarily dependent on the length of the channel, indicating that large particles (∼75μm) must originate from within a kilometer below the surface, while smaller particles (∼3μm) can originate from only hundreds of meters below the surface. We further show that the velocity of the flow, exit temperature and nucleation depend directly on the exit-to-throat size ratio. We find that the channel geometry evolves within a few tens of hours until an equilibrium is reached, when considering the accretion of gas to the walls, or sublimation of ice from the walls. As the channel closes due to accretion, the flow becomes thinner, which in turn reduces accretion. After around 70 h, the accretion is sufficiently slowed such that the geometry does not evolve anymore. This equilibrium geometry produces higher Mach numbers and a larger particle size and solid fraction compared to the initial geometry.@en