Magnetic seeding coagulation (MSC) process has been used to accelerate flocs sedimentation with an applied magnetic field, offering large handling capacity and low energy consumption. The interactions of three typical Al species, aluminum chloride (AlCl3), Al13O4(OH)247+ polymer (Al13), and (AlO4)2Al28(OH)5618+ polymer (Al30), with magnetic particles (MPs) were examined to clarify the MSC process. In traditional coagulation (TC) process, the aggregation of primary Ala-dissolved organic matter (DOM) complexes with in-situ-formed polynuclear species generated a large average floc size (226 μm), which was proved to be efficient for DOC removal (52.6%). The weak connections between dissolved Ala-DOM complexes and MPs led to the negligible changes of dissolved Al after seeding with MPs in AlCl3. A significant interaction between MPs and Al13 was observed, in which the MPs-Al13-DOM complexes were proposed to be responsible for the significant improvement of DOC removal (from 47% to 52%) and residual total Al reduction (from 1.05 to 0.27 mg Al L−1) with MPs addition. Al30 produced a lower floc fractal dimension (Df = 1.88) than AlCl3 (2.08) and Al13 (1.99) in the TC process, whereas its floc strength (70.9%) and floc recovery (38.5%) were higher than the others. Although more detached fragments were produced with MPs addition, the effective sedimentation of these fragments with the applied magnetic field led to the decrease of residual turbidity and colloidal Al in Al30. The dependence of coagulation behavior to MPs and different Al species can be applied to guide the application of an effective MSC process.@en

Mass balance analysis of ice sheets is a key component to understand the effects of global warming. A significant component of ice sheet and shelf mass balance is iceberg calving, which can generate large tsunamis endangering human beings and coastal infrastructure. Such iceberg-tsunamis have reached amplitudes of 50 m and destroyed harbours. Calving icebergs interact with the surrounding water through different mechanisms and we investigate five; A: capsizing, B: gravity-dominated fall, C: buoyancy-dominated fall, D: gravity-dominated overturning and E: buoyancy-dominated overturning. Gravity-dominated icebergs essentially fall into the water body whereas buoyancy-dominated icebergs rise to the water surface. We find with unique large-scale laboratory experiments that iceberg-tsunami heights from gravity-dominated mechanisms (B and D) are roughly an order of magnitude larger than from A, C and E. A theoretical model for released iceberg energy supports this finding and the measured wave periods upscaled to Greenlandic outlet glaciers agree with field observations. Whilst existing empirical equations for landslide-tsunamis establish estimates of an upper envelope of the maximum iceberg-tsunami heights, they fail to capture the physics of most iceberg-tsunami mechanisms.@en