Chemical hydrograph separation using electrical conductivity and digital filters is applied to quantify runoff components in the 1,640 km2 semi-arid Kaap River catchment and its subcatchments in South Africa. A rich data set of weekly to monthly water quality data ranging from 1978 to 2012 (450 to 940 samples per site) was analysed at 4 sampling locations in the catchment. The data were routinely collected by South Africa's national Department of Water and Sanitation, using standard sampling procedures. Chemical hydrograph separation using electrical conductivity (EC) as a tracer was used as reference and a recursive digital filter was then calibrated for the catchment. Results of the two-component hydrograph separation indicate the dominance of baseflow in the low flow regime, with a contribution of about 90% of total flow; however, during the wet season, baseflow accounts for 50% of total flow. The digital filter parameters were very sensitive and required calibration, using chemical hydrograph separation as a reference. Calibrated baseflow estimates ranged from 40% of total flow at the catchment outlet to 70% in the tributaries. The study demonstrates that routinely monitored water quality data, especially EC, can be used as a meaningful tracer, which could also aid in the calibration of a digital filter method and reduce uncertainty of estimated flow components. This information enhances our understanding of how baseflow is generated and contributed to streamflow throughout the year, which can aid in quantification of environmental flows, as well as to better parameterize hydrological models used for water resources planning and management. Baseflow estimates can also be useful for groundwater and water quality management.@en

This study aims at improving the hydrological process understanding of the semi-arid and transboundary Incomati river basin to enable better water management. Comprehensive statistical and trend analysis of rainfall and streamflow were conducted, and the Indicators of Hydrological Alteration tool was deployed to describe the streamflow regime and trends over time. Land use and land cover change, particularly the conversion of natural vegetation into forest plantation, the expansion of irrigated agriculture and the flow regulation due to dam operation were identified as critical drivers of flow regime alteration. Hydrograph separation using long-term hydrochemical data at seasonal scale, and hydrochemical and isotope data at event scale were performed to quantify runoff components. A novel methodology to calibrate recursive digital filters using routinely collected water quality data was developed and tested in the catchment. This method allows for estimation of daily baseflow from readily available daily streamflow data. Dominant runoff generation zones were mapped using the Height Above Nearest Drainage approach. The hydrological model STREAM was then employed, informed by the runoff generation zones mapping and the process understanding gained in the catchment, as well as remote sensing data. The study provides the basis for better operational water management in the catchment.@en