The controllability of mining is a key factor affecting the commercial application of methane hydrates, and the addition of chemical additives can significantly accelerate the mining process. However, the effect of additive concentration on hydrate decomposition is not yet well understood. In this study, we systematically investigate the effect of ethanol concentration on the decomposition of methane hydrate under varying thermodynamic conditions using molecular dynamics (MD) simulations. To quantitatively characterize the decomposition process and mechanism of methane hydrates, the combination of angular order parameter (AOP), radial distribution function (RDF), mean square displacement (MSD), diffusion coefficients and system energy was for the first time used. The results showed that the addition of ethanol contributed to the formation of methane bubbles and accelerated the decomposition of hydrates. The mass transfer effect of ethanol molecules and the reconstruction of the hydrogen bond network of water molecules determined the stability of hydrates. From 0 to 40 mol% ethanol concentration, the hydrate decomposition increased with increasing the concentration of ethanol. Both increasing the temperature and decreasing the pressure are beneficial to the decomposition of the hydrate system. These results provide the selection of optimal ethanol concentration for the decomposition of methane hydrate and reveal its decomposition mechanism, and shed important light for the controllable production of gas hydrates.@en

Fossil fuel resources are invaluable to economic growth and social development. Understanding the formation and distribution of fossil fuel resources is critical for the search and exploration of them. Until now, the vertical distribution depth of fossil fuel resources has not been confirmed due to different understandings of their origins and the substantial variation in reservoir depths from basin to basin. Geological and geochemical data of 13 634 source rock samples from 1286 exploration wells in six representative petroliferous basins were examined to identify the maximum burial depth of active source rocks in each basin, which is referred to in this study as the active source rock depth limit (ASDL). Beyond the ASDL, source rocks no longer generate or expel hydrocarbons and become inactive. Therefore, the ASDL also sets the maximum depth for fossil fuel resources. The ASDLs of basins around the world are found to range from 3000 to 16 000 m, while the thermal maturities (Ro) of source rocks at the ASDLs are almost the same, with Ro ≈ 3:5±0:5 %. The Ro of 3.5% can be regarded as a general criterion to identify ASDLs. High heat flow and more oil-prone kerogen are associated with shallow ASDLs. In addition, tectonic uplift of source rocks can significantly affect ASDLs; 21.6 billion tons of reserves in six representative basins in China and 52 926 documented oil and gas reservoirs in 1186 basins around the world are all located above ASDLs, demonstrating the universal presence of ASDLs in petroliferous basins and their control on the vertical distribution of fossil fuel resources. The data used in this study are deposited in the repository of the PANGAEA database at: https://doi.org/10.1594/PANGAEA.900865 (Pang et al., 2019).@en

In view of enhanced oil recovery, the adsorption behavior of surfactants is usually monitored on smooth model rock surfaces using quartz crystal microbalance with dissipation (QCM-D). However, this is an impractical situation as the effect of the surface roughness of reservoir rocks and its role in surfactant adsorption processes are not yet completely understood. The coupling of electrochemical techniques and QCM-D in one analysis setup (EQCM-D) provides a new methodology to explore complex surfactant adsorption processes. In this work, a uniform, rough, and well-covered model CaCO3 surface was obtained on gold and platinum sensors to model carbonate rocks. This was achieved by the electrochemically formed hydroxide ions in the presence of bicarbonate and calcium ions, by which the controlled deposition of CaCO3 resulted in sensor surface coverages in the range 35-40%. Before using the deposited CaCO3 surfaces, the adsorption of anionic surfactant alcohol alkoxy sulfate (AAS) on a smooth commercially available CaCO3 surface was studied with varying CaCl2 concentrations. For the first time, the structure and characteristics of the formed AAS layer were quantitatively described, indicating the formation of an incomplete bilayer. Compared to the smooth CaCO3 surface, an increase in the frequency shift from 5 to 15 times was observed in sensors covered with rough CaCO3 deposit. This observation was primarily attributed to the rougher surfaces that possess more adsorption sites for AAS binding and also to the effect of liquid trapping, inducing additional frequency shifts. The obtained results show that surfactant adsorption on rough surfaces was vastly different from that on smooth surfaces, and they provide a better understanding of the adsorption behavior of surfactants to mineral surfaces. @en