Accurate identification of lithium-ion battery parameters is essential for estimating battery states and managing performance. However, the variation of battery parameters over the state of charge (SOC) and the nonlinear dependence of the open-circuit voltage (OCV) on the SOC complicate the identification process. In this work, we develop a continuous-time LPV system identification approach to identify the SOC-dependent battery parameters and the OCV-SOC mapping. We model parameter variations using cubic B-splines to capture the piecewise nonlinearity of the variations and estimate signal derivatives via state variable filters, facilitating CT-LPV identification. Battery parameters and the OCV-SOC mapping are jointly identified by solving L1-regularized least squares problems. Numerical experiments on a simulated battery and real-life data demonstrate the effectiveness of the developed method in battery identification, presenting improved performance compared to conventional RLS-based methods.

Accurate identification of lithium-ion (Li-ion) battery parameters is essential for managing and predicting battery behavior. However, existing discrete-time methods hinder the estimation of physical parameters and face the fast-slow dynamics problem of the battery. In this paper, we develop a continuous-time approach that enables the estimation of battery parameters directly from sampled data. This method avoids discretization errors in converting continuous-time models into discrete-time ones. Moreover, the developed method is capable of jointly identifying the open-circuit voltage (OCV) and the state of charge (SOC) relation of batteries without utilizing offline OCV tests. By modeling the OCV-SOC curve as a cubic B-spline, we represent the piecewise nonlinearity of the OCV curve with high fidelity, facilitating its estimation. By solving a rank and L1 regularized least squares problem, we identify battery parameters and the OCV-SOC relation directly from the battery’s dynamic data. Simulated and real-life data validate the effectiveness of the developed method.

This paper develops a novel approach for online Lithium-ion (Li-ion) battery model identification and state of charge (SOC) estimation. To account for the SOC-dependent battery dynamics and the static nonlinearity between the open-circuit voltage (OCV) and SOC, we formulate a grey box nonlinear state-space model, in which elements depend on SOC in a polynomial way. For model identification, we propose an online concurrent state and parameter estimation by alternating the recursive least squares algorithm and particle filter; the SOC is computed via Coulomb counting during the modeling. The identified grey box model is then applied for SOC estimation using the particle filter. Simulation with real-world battery measurements demonstrates the effectiveness of the model structure and the estimation approach, which is reflected in accurate terminal voltage estimation and nonlinear OCV-SOC relation, and superior performance regarding SOC estimation compared to state-of-the-art approaches.

Identification of lithium-ion (Li-ion) battery models is essential for enhancing the operation of electrical vehicles. This paper develops a novel approach for estimating the equivalent circuit model (ECM) of Li-ion batteries and reconstructing the open-circuit voltage (OCV) and state of charge (SOC) relationship. We formulate the OCV-SOC relation as a piecewise affine (PWA) function and estimate its coefficients and the Markov parameters (impulse response) of the ECM via l₁-regularized least squares. The state space model of the ECM is derived through the Ho-Kalman algorithm. Experiments with simulated and real-life battery data demonstrate the method's effectiveness and advantages with respect to the state of the art.

To solve unmodeled optimization problems with hard constraints, this paper proposes a novel zeroth-order approach called Safe Zeroth-order Optimization using Linear Programs (SZO-LP). The SZO-LP method solves a linear program in each iteration to find a descent direction, followed by a step length determination. We prove that, under mild conditions, the iterates of SZO- LP have an accumulation point that is also the primal of a KKT pair. We then apply SZO-LP to solve an Optimal Power Flow (OPF) problem on the IEEE 30-bus system. The results demonstrate that SZO-LP requires less computation time and samples compared to state-of-the-art approaches.