Asphalt aging often leads to rapid degradation of road performance, which seriously affects the service life of asphalt pavement. Exploring the influence of asphalt oil sources, asphalt grades, and filler types on asphalt microcharacteristics in the asphalt aging process can provide an essential reference to guide asphalt pavement maintenance. In this study, we selected seven kinds of asphalt and three fillers commonly used in China for research. The pressurized aging vessel (PAV) and homemade ultraviolet (UV) aging equipment were used to perform thermo-oxidative aging and UV aging tests, respectively, of asphalt. The microcharacteristics of asphalt before and after aging were analyzed via attenuated total reflectance fourier transformation infrared spectroscopy and nuclear magnetic resonance ¹H spectroscopy. The results show that the oil source of asphalt exerted the most significant influence on the microcharacteristics of the aged asphalt, while the effect of the asphalt grade was relatively limited. The addition of fillers did not affect the aging mechanism of asphalt. UV and PAV aging generated apparent differences in the changes in the aged asphalt microstructure.

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The chemical and rheological properties of polymer modified bitumen incorporating bio-oil derived from waste cooking oil (WCO) were investigated in this paper. At first, the chemical composition and mixing mechanism of the experimental materials were analysed from the perspective of functional group, and the influence of bio-oil on the activation energy was also researched. Then, the effect of bio-oil on the rotational viscosities of polymer modified bitumen and construction temperatures of corresponding mixtures was studied. Finally, the shear and bending rheological properties of polymer modified bitumen containing bio-oil were investigated. The results show that the bio-oil and styrene–butadiene–styrene (SBS) modified bitumen is mainly physically mixed, the addition of bio-oil decreases the activation energy of SBS modified bitumen. Additionally, the SBS modified bitumen containing bio-oil has lower viscosity values, and corresponding mixtures also have lower construction temperatures. Furthermore, the addition of bio-oil in SBS modified bitumen reduces the shear modulus and increases the bending creep compliance, which means bio-oil has positive effect on the low-temperature thermal cracking resistance performance while sacrificing the high-temperature rutting resistance performance to some extent. Therefore, the incorporation of WCO-based bio-oil in polymer modified bitumen is a promising technique to be used in cold regions where the low-temperature problems are more crucial.@en

For practical application of lithium-oxygen batteries, one of the challenges is the development of efficient bifunctional electrocatalysts for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) in cathode. In this work, perovskite Sr _0.9 Y _0.1 CoO _3-δ nanorods are synthesized by an electrospinning method. The performance of the Li-O ₂ cell with Sr _0.9 Y _0.1 CoO _3-δ catalysts is better than that of the cell only with Super-P. Furthermore, modification of CoO nanoparticles on the cathode can provide an obviously improved electrochemical performance with a reduced voltage gap (∼80-140 mV), which is ascribed to the superior catalytic activity of CoO nanoparticles toward OER. All of these results demonstrate that the perovskite Sr _0.9 Y _0.1 CoO _3-δ is an efficient bifunctional electrocatalyst for lithium-oxygen batteries, and the incorporation of CoO nanoparticles is an effective approach for improving the cathode performance as well.

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