Oxidative aging induces significant stiffening of asphalt binders that leads to a pronounced reduction in the overall durability of asphalt pavements. The strategic implementation of antioxidant additives provides a potential solution to alleviate this issue. This work presents results from the second phase of the global consortium for antioxidants research aimed at investigating the effectiveness of potential antioxidants in increasing the durability of asphalt binders. Sixteen laboratories around the world participated in this effort and a total of 28 binders from diverse geographical regions were tested. Two promising antioxidants, namely zinc diethyldithiocarbamate (ZDC) and kraft lignin were evaluated in this phase and blended with the binders at specific proportions. Subsequently, a comprehensive investigation was conducted to assess rheological characteristics and chemical properties of the various blends, utilising Dynamic Shear Rheometer (DSR) measurements and Fourier Transform Infrared (FTIR) Spectroscopy. The findings indicate that additives such as ZDC hold considerable promise as an effective antioxidant, particularly when considering a wide diversity of binders. In general, its incorporation does not compromise the rutting performance of the binders and significantly improves fatigue performance. Therefore, research efforts should be focused on exploring additional facets to assess its practical applicability in field.

The chemical characterization of bitumen type and ageing state are fundamental in determining structural and mechanical properties of bitumen. This work aims to classify various bitumen types at different ageing states and to identify the primary chemical differences relevant to the classification. Fourier transform infrared (FTIR) spectral data of eight bitumen types at five ageing states were analyzed using a chemometric procedure that incorporates principal component analysis (PCA), linear discriminant analysis (LDA) models, variable selection methods. The models presented results of high accuracy in differentiating bitumen type and ageing state. The results show that the spectral regions that describe the aliphatic and aromatic bonds are critical to the identification of bitumen types. The chemical changes due to bitumen ageing are mainly revealed at the region of 1800–900 cm-1. This chemometric method is instructive for the characterization of chemical bitumen properties.

The rejuvenation efficiency of aged bitumen is the main concern when developing rejuvenating agents. It is necessary to develop a method to assess the efficiency of rejuvenators using rheological parameters in the whole frequency region. To this end, the 2S2P1D micromechanics model is adopted to fit the entire G∗ master curves of various rejuvenated bitumen, and the influence of rejuvenator type/dosage and aging grade of bitumen on the whole G∗ master curve and chemical indices are investigated. Critical parameters for evaluating rejuvenation efficiency derived from viscoelastic models and chemical characterizations are proposed. Furthermore, the potential relationships between the rheological model-based parameters (E _∞, δ, β, and τ) and chemical indices (carbonyl index CI and sulfoxide index SI) are explored. The results indicate that rejuvenators restore the δ, τ, CI, and SI values of aged bitumen towards the virgin bitumen level. The E _∞ parameter is not applicable to evaluate the rejuvenation efficiency of engine-oil and naphthenic-oil rejuvenators, but the positive E _∞R values of bio-oil and aromatic-oil rejuvenated bitumen are detected. All rejuvenators fail to restore the β parameter of aged bitumen. The τ and CI parameters are selected as critical evaluation indicators from the perspective of viscoelastic models and chemical characteristics. Linear correlations between all rheological parameters and chemical indices are observed and established.

Water transport is one of the major factors responsible for moisture damage in asphalt pavements. To study the thermodynamics and kinetics of water transport in bitumen and to uncover microscale mechanisms of moisture-induced damage, molecular dynamics simulations were performed for up to 600 ns for water–bitumen systems with realistic water contents that varied from 0 to 1.76 wt%. Hydrogen bonding interactions and clustering of water molecules at various combinations of temperature and water content were investigated, and their effects on the self-diffusion coefficient of water and bitumen properties are computed and discussed. It is shown that the saturated water concentration in bitumen is small, especially at low temperatures, and additional water molecules tend to form large water clusters via hydrogen bonding, indicating micro-phase separation of the water and bitumen phases inside the simulation box. Hydrogen bonding and water clustering play a crucial role on the magnitude of the self-diffusion coefficient of water. Physical properties of bitumen that include viscosity and cohesive energy are affected by water. The presence of large water clusters is indicative of how degradation in cohesion is observed on the microscale.

RILEM TC-279 WMR task group TG 1 studied the performance of waste Polyethylene (PE) in bituminous binders and bituminous mixtures. Several laboratories participated in this study following a common protocol. Locally sources aggregates and bituminous binder and same source of waste PE were utilized. The binder experiments showed that at high temperatures, using MSCR tests, PE modified blends had better resistance to permanent deformation in comparison to the non modified binder. Whereas at intermediate temperatures, using the LAS tests, fatigue performance of the PE blends could withstand more loading cycles under low strains; however, it could sustain less loading cycles under high strains due to the increase in brittleness. Dry process was used for the mixture experiments in order to bypass the stability and inhomogeneity experience that was observed at the binder scale. The PE modified mixtures showed improved workability and increased strength. The higher the PE dosage, the higher the ITS increase with respect to the values measured for the control materials (i.e., without any plastic waste) thanks to the improved cohesion of the plastic modified mastic. The stiffness experiments tended to show an improved performance with a lower time dependence and a higher elasticity when plastic was added. The cyclic compression tests demonstrated a reduced creep rate along with a higher creep modulus thanks to the addition of PE; similar conclusions can be drawn from the experimental findings coming from wheel tracking test. Furthermore, acceptable and often improved moisture resistance was observed for PE modified materials.

To purify severe air pollution in traffic-intensive urban areas and tunnels, an innovative type of photocatalytic micro-surfacing mixture (PMM) was designed, which was enhanced by polypropylene (PP) fiber and nano-TiO₂. In this work, the road performance of sixteen PMMs with the different contents of PP and nano-TiO₂ were evaluated by wet-track abrasion test, wheel rutting deformation test and low-temperature splitting test. The vehicle exhaust (VE) gas degradation capacity of sixteen PMMs was characterized under ultraviolet (UV) light and visible light conditions. The life cycle assessment (LCA) methodology was applied to evaluate the environmental impact of PMM. The results showed that the road performances of PMM were improved with the increase of the PP fibers amount. The VE gas degradation capacity was significantly enhanced with the increase of nano-TiO₂ amount. PMM with 0.2 wt% PP fibers and 60 wt% replacement of mineral filler with nano-TiO₂ was a viable alternative to improve photocatalytic degradation of VE in pavement engineering. In addition, the modified micro-surfacing mixture facilitates a significant reduction in energy consumption and greenhouse gas emissions.

Asphalt aging often leads to rapid degradation of road performance, which seriously affects the service life of asphalt pavement. Exploring the influence of asphalt oil sources, asphalt grades, and filler types on asphalt microcharacteristics in the asphalt aging process can provide an essential reference to guide asphalt pavement maintenance. In this study, we selected seven kinds of asphalt and three fillers commonly used in China for research. The pressurized aging vessel (PAV) and homemade ultraviolet (UV) aging equipment were used to perform thermo-oxidative aging and UV aging tests, respectively, of asphalt. The microcharacteristics of asphalt before and after aging were analyzed via attenuated total reflectance fourier transformation infrared spectroscopy and nuclear magnetic resonance ¹H spectroscopy. The results show that the oil source of asphalt exerted the most significant influence on the microcharacteristics of the aged asphalt, while the effect of the asphalt grade was relatively limited. The addition of fillers did not affect the aging mechanism of asphalt. UV and PAV aging generated apparent differences in the changes in the aged asphalt microstructure.

Bitumen in asphalt pavements reacts slowly with atmospheric oxygen, resulting in oxidative ageing. This oxidative reaction is strongly dependent on the physical diffusion of the oxygen into the bitumen. This study aims to use molecular dynamics (MD) simulation to investigate the oxygen diffusion into the bitumen film and analyse the effects of anti-ageing compounds (AACs) on the oxygen diffusion. The MD diffusion simulations using a Polymer Consistent Force Field (PCFF) were conducted on a bitumen-air bi-layer model at different temperatures. Fick's second law was used to calculate the diffusion coefficient of the oxygen in the bitumen film. It is found that the oxygen diffusion coefficients ranged from 6.67 × 10⁻¹⁰ to 7.45 × 10⁻¹¹ m²/s for the unmodified and AAC-modified bitumens at the simulating temperatures of 25, 50 and 100 °C. Irganox acid and DLTDP (Dilauryl thiodipropionate):furfural showed two different anti-aging mechanisms, i.e., reducing the oxygen physical diffusion and controlling the chemical oxidative reaction. Reducing the oxygen diffusivity by constructing a network in the bitumen to retard oxygen diffusion and increase the transport path is an efficient way to slow down the bitumen aging without the antioxidant consumption. This work proposed a MD-based computational approach, contributing to 1) determination of the oxygen diffusion coefficient of the existing bitumen that is extremely challenging for the experimental measurement and 2) instruction of developing new antioxidant.

In this study, a series of viscosity tests were performed to investigate various conditions, i.e. temperature, shear rate and dilution level, on the curing behavior of epoxy bitumen. The results show that curing rate of epoxy bitumen increased with temperature; high shear rate would interfere the formation of crosslinks in epoxy bitumen, resulting in a negative effect on curing rate; diluting epoxy bitumen by a base bitumen was an effective way to control the curing rate and reduce the material cost. Considering the workability and durability of paving materials, it is recommended that dilution level of epoxy bitumen is 25%, mixing rate is 20 r/min, curing temperature is 130 ℃, and the pavement construction should be finished within 5 hours.