Since the industrial revolution the use of fossil fuels has increased exponentially, this increase caused a higher concentration of carbon dioxide in the atmosphere, which is responsible for climate change. To prevent a large-scale change of the earth’s climate humanity needs to switch to renewable energy sources. A large drawback of current renewable energy sources is that they almost all exclusively produce electricity which is hard to store for long periods of time. A possible solution to this energy storage issue is the electrochemical reduction of CO2 with electricity from renewable sources. Catalysts used for this process are transition metals but there are several problems that prevent large-scale implementation. Two fundamental problems with these catalysts are: Low activity causing low reaction rates, and low selectivity causing the formation of undesired products. A possible solution was proposed by Lim et al. (2014)1 where they suggested doping a silver electrode with sulphur to enhance the selectivity and activity for carbon monoxide production. This proposal was put the test in this thesis where silver was doped with sulphur by two different methods and were characterized by different techniques and tested at four different potentials. The method where a sample was immersed in a sulphur containing solution and subsequently annealed proofed to be the most effective way to dope a silver electrode. With the help of gas chromatography it was found out that at lower overpotentials the addition of sulphur is beneficial to its performance to produce CO but at higher potentials this advantage is lost. However if the results of this thesis are compared to literature it is clear that doping with sulphur is not effective. Furthermore it was seen that the sulphur doped Ag electrodes were not very stable and therefore not suited for large-scale implementation.