The application of reverse osmosis (RO) membranes in water treatment has rapidly grown over the last few decades thanks to the continuous advancements in both design and operation. However, RO membrane fouling still remains a key challenge. Fouling can cause a decline in membrane permeability, which requires higher operational energy and more frequent membrane cleaning/replacement to maintain stable water production, which eventually results in increased O&M costs. Particulate fouling, due to the deposition of particles and colloids onto RO membranes, is one of the types of fouling persistently experienced in RO systems. Therefore, there is a real need for a reliable method to predict particulate fouling in order to effectively monitor and control the performance of RO systems....@en

This study aimed to quantify the effect of membrane surface porosity on particulate fouling predicted by the MFI-UF method at constant flux. Firstly, the surface porosity of polyethersulfone UF membranes (5–100 kDa) was determined using ultra-high resolution SEM. Thereafter, the MFI-UF was measured using suspensions of polystyrene particles (75 nm), which were pre-washed to remove surfactant and particle fractions smaller than the pores of MFI-UF membranes, thus ensuring complete retention of particles during MFI-UF measurements. Consequently, the MFI-UF values of washed polystyrene particle suspensions were independent of the pore size and depended only on the surface porosity of MFI-UF membrane. The results showed that the membrane surface porosity decreased with MWCO from 10.5% (100 kDa) to 0.6% (5 kDa), and consequently the MFI-UF increased from 3700 to 8700 s/L2, respectively. This increase in MFI-UF was attributed to the non-uniform distribution of membrane pores, which is exacerbated as surface porosity decreases. Consequently, preliminary correction factors of 0.4–1.0 were proposed for MFI-UF measured with UF membranes in the range 5–100 kDa. Finally, the surface porosity correction was applied to predict particulate fouling in a full-scale RO plant. However, additional research is required to establish correction factors for different types of feed water.@en

This study aims at applying and verifying the MFI-UF method to predict particulate fouling in RO plants. Two full-scale RO plants treating surface water, with average capacity of 800–2000 m3/h, were studied. Firstly, the MFI-UF of RO feed and concentrate was measured using 5–100 kDa membranes at same flux applied in the RO plants (20–26 L/m2.h). Subsequently, the particle disposition factor (Ω) was calculated to simulate particle deposition in RO cross-flow filtration. Finally, particulate fouling rates were predicted based on MFI-UF and Ω, and compared with the actual fouling rates in the plants. For plant A, the results showed that the fouling rates predicted using MFI-UF measured with 100 kDa membrane have the best agreement with the actual fouling (with 3–11 % deviation). For plant B, the fouling rates predicted based on both 10 and 100 kDa membranes agree well with the actual fouling (with 2 % and 15 % deviation, respectively). However, the fouling predicted based on 5 kDa membrane is considerably overestimated for both plants, which is attributed to the effect of the low surface porosity of 5 kDa membrane. More widespread applications of MFI-UF in full-scale RO plants are required to demonstrate the most suitable MFI-UF membranes for fouling prediction.@en

This study aimed to calibrate and validate the MFI-UF method in order to ensure the accuracy of particulate fouling measurements in RO. Firstly, the MFI-UF calibration was examined using two solutions of standard particles (dextran and polystyrene). Two main criteria were investigated: (i) MFI-UF linearity with particle concentrations at both low and high ranges of fouling potential and (ii) the reproducibility of MFI-UF linearity. Dextran solutions showed a strong MFI-UF linearity over the entire range of measured MFI-UF. However, the linearity was not reproducible, and different batches of dextran prepared under the same conditions produced very variable results. For polystyrene solutions, the MFI-UF linearity was verified at the higher range of MFI-UF (>10,000 s/L2), while the MFI-UF at the lower range (<5000 s/L2) appeared to be underestimated. Secondly, MFI-UF linearity was investigated using natural (surface) water under a wide range of testing conditions (at 20–200 L/m2·h using 5–100 kDa membranes). Strong MFI-UF linearity was obtained over the entire range of measured MFI-UF (up to 70,000 s/L2). Thus, the MFI-UF method was validated to measure different levels of particulate fouling in RO. However, future research focusing on MFI-UF calibration is still required through the selection, preparation, and testing of heterogeneous mixtures of standard particles.@en