We theoretically show that IV-VI semiconducting compounds with lowerature rhombohedral crystal structure represent a new potential platform for topological semimetals. By means of minimal k·p models, we find that the two-step structural symmetry reduction of the higherature rocksalt crystal structure, comprising a rhombohedral distortion along the [111] direction followed by a relative shift of the cation and anion sublattices, gives rise to topologically protected Weyl semimetal and nodal line semimetal phases. We derive general expressions for the nodal features and apply our results to SnTe, showing explicitly how Weyl points and nodal lines emerge in this system. Experimentally, the topological semimetals could potentially be realized in the lowerature ferroelectric phase of SnTe, GeTe, and related alloys.

We discuss recent advances in the study of topological insulators protected by spatial symmetries by reviewing three representative, theoretical examples. In three dimensions (3D), these states of matter are generally characterized by the presence of gapless boundary states at surfaces that respect the protecting spatial symmetry. We discuss the appearance of these topological states in both crystals with negligible spin–orbit coupling and a fourfold rotational symmetry, as well as in mirror-symmetric crystals with sizable spin–orbit interaction characterized by the so-called mirror Chern number. Finally, we also discuss similar topological crystalline states in one-dimensional (1D) insulators, such as nanowires or atomic chains, with mirror symmetry. There, the prime physical consequence of the non-trivial topology is the presence of quantized end charges.