JG

J. Grievink

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High Pressure Polymerisation of Ethylene - Influence of extensions to Goto's kinetic model and data set on the prediction of process conditions and product properties

Part 1: Influence of conversion on the termination rate coefficient; introduction of a conversion dependent termination model

In this report a conversion dependent termination model, developed by Buback, is investigated, and finally implemented in the kinetic model and data set derived by Goto. The report begins with an overview of the reactions in the free-radical mechanism of the high pressure ethylen ...