Recommender Systems (RS) influence everyday decisions, yet most remain optimized for short-term engagement or commercial gain. RS4SD aims to shift this focus by exploring how RS can contribute to sustainable development through behavioral change and nudging strategies. Aligned with the UN Sustainable Development Goals (SDG), RS4SD will highlight applications that promote responsible consumption, sustainable mobility, healthy eating, and digital well-being. In particular, we will focus on how AI and RS can be designed to foster sustainable behaviors through multi-objective optimization and ethically aligned interventions. These objectives are directly tied to the UN SDG, and we welcome all contributions showcasing RS in support of these goals. A central theme of the workshop is the integration of behavioral science and AI to design interventions that guide users toward more sustainable and healthier choices while preserving individual autonomy. Topics of interest include multi-objective recommendation, health-aware RS, eco-friendly product and tourism RS, as well as novel evaluation metrics that go beyond accuracy to capture societal impact. RS4SD will bring together researchers, stakeholders and practitioners from RS, AI, sustainability, and behavioral science to share models, datasets, frameworks, and real-world use cases. The workshop encourages interdisciplinary collaboration and aims to build a community dedicated to responsible, behavior-aware RS that benefit both individuals and society.