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Chao Zhang

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Journal article (2022) - Chao Zhang, Yiqiu Tan, Yangming Gao, Yongkang Fu, Jilu Li, Shuai Li, Xingye Zhou
The service performances of asphalt pavement, especially rutting, will be inevitably affected by climate change. However, existing studies have generally focused on the rutting depth and rutting life, and thus became insufficient for comprehensively evaluating the influence of climate change on rutting over the service life. A resilience assessment method for asphalt pavement rutting is developed to solve the above problem. First, the original resilience method is extended to fit the system whose performance level continues to decline. Then, the calculation formulas of rutting resilience are derived by combining the rutting prediction model and the level assessment model. Subsequently, the influence degrees of climate change in representative cities on rutting resilience are studied. The results suggest that neglecting climate change in rutting design of asphalt pavement will lead to insufficient resilience, especially in northern China. Furthermore, the predicted temperature under RCP8.5 should be employed for asphalt pavement design. ...
Journal article (2022) - Yangming Gao, Yuqing Zhang, Chao Zhang, Xueyan Liu, Ruxin Jing
Bitumen in asphalt pavements reacts slowly with atmospheric oxygen, resulting in oxidative ageing. This oxidative reaction is strongly dependent on the physical diffusion of the oxygen into the bitumen. This study aims to use molecular dynamics (MD) simulation to investigate the oxygen diffusion into the bitumen film and analyse the effects of anti-ageing compounds (AACs) on the oxygen diffusion. The MD diffusion simulations using a Polymer Consistent Force Field (PCFF) were conducted on a bitumen-air bi-layer model at different temperatures. Fick's second law was used to calculate the diffusion coefficient of the oxygen in the bitumen film. It is found that the oxygen diffusion coefficients ranged from 6.67 × 10−10 to 7.45 × 10−11 m2/s for the unmodified and AAC-modified bitumens at the simulating temperatures of 25, 50 and 100 °C. Irganox acid and DLTDP (Dilauryl thiodipropionate):furfural showed two different anti-aging mechanisms, i.e., reducing the oxygen physical diffusion and controlling the chemical oxidative reaction. Reducing the oxygen diffusivity by constructing a network in the bitumen to retard oxygen diffusion and increase the transport path is an efficient way to slow down the bitumen aging without the antioxidant consumption. This work proposed a MD-based computational approach, contributing to 1) determination of the oxygen diffusion coefficient of the existing bitumen that is extremely challenging for the experimental measurement and 2) instruction of developing new antioxidant. ...