Bubbles in complex fluids are often desirable, and sometimes simply inevitable, in the processing of formulated products. Bubbles can rise by buoyancy, grow or dissolve by mass transfer, and readily respond to changes in pressure, thereby applying a deformation to the surrounding complex fluid. The deformation field around a stationary, spherical bubble undergoing a change in radius is simple and localized, thus making it suitable for rheological measurements. This article reviews emerging approaches to extract information on the rheology of complex fluids by analysing bubble dynamics. The focus is on three phenomena: changes in radius by mass transfer, harmonic oscillations driven by an acoustic wave, and bubble collapse. These phenomena cover a broad range of deformation frequencies, from 10−4–106 Hz, thus paving the way to broadband microrheology using bubbles as active probes. The outstanding challenges that need to be overcome to achieve a robust technique are also discussed.@en

Colloidal gels possess a memory of previous shear events, both steady and oscillatory. This memory, embedded in the microstructure, affects the mechanical response of the gel, and therefore enables precise tuning of the material properties under careful preparation. Here we demonstrate how the dynamics of a deformable inclusion, namely a bubble, can be used to locally tune the microstructure of a colloidal gel. We examine two different phenomena of bubble dynamics that apply a local strain to the surrounding material: dissolution due to gas diffusion, with a characteristic strain rate of ∼10-3 s-1; and volumetric oscillations driven by ultrasound, with a characteristic frequency of ∼104 s-1. We characterise experimentally the microstructure of a model colloidal gel around bubbles in a Hele-Shaw geometry using confocal microscopy and particle tracking. In bubble dissolution experiments, we observe the formation of a pocket of solvent next to the bubble surface, but marginal changes to the microstructure. In experiments with ultrasound-induced bubble oscillations, we observe a striking rearrangement of the gel particles into a microstructure with increased local ordering. High-speed bright-field microscopy reveals the occurrence of both high-frequency bubble oscillations and steady microstreaming flow; both are expected to contribute to the emergence of the local order in the microstructure. These observations open the way to local tuning of colloidal gels based on deformable inclusions controlled by external pressure fields.@en

According to everyone's experience, predicting the weather reliably over more than 8d seems an impossible task for our best weather agencies. At the same time, politicians and citizens are asking scientists for climate projections several decades into the future to guide economic and environmental policies, especially regarding the maximum admissible emissions of CO2. To what extent is this request scientifically admissible? In this review we will investigate this question, focusing on the topic of predictions of transitions between metastable states of the atmospheric or oceanic circulations. Two relevant examples are the switching between zonal and blocked atmospheric circulation at mid-latitudes and the alternation of El Nino and La Nina phases in the Pacific Ocean. The main issue is whether present climate models, which necessarily have a finite resolution and a smaller number of degrees of freedom than the actual terrestrial system, are able to reproduce such spontaneous or forced transitions. To do so, we will draw an analogy between climate observations and results obtained in our group on a laboratory-scale, turbulent, von Karman flow in which spontaneous transitions between different states of the circulation take place. We will detail the analogy, investigate the nature of the transitions and the number of degrees of freedom that characterize the latter, and discuss the effect of reducing the number of degrees of freedom in such systems. We will also discuss the role of fluctuations and their origin and stress the importance of describing very small scales to capture fluctuations of correct intensity and scale.@en

Yield-stress fluids naturally trap small bubbles when their buoyancy applies an insufficient stress to induce local yielding of the material. Under acoustic excitation, trapped bubbles can be driven into volumetric oscillations and apply an additional local strain and stress that can trigger yielding and assist their release. In this paper we explore different regimes of microbubble oscillation and translation driven by an ultrasound field in a model yield-stress fluid, a Carbopol microgel. We first analyse the linear bubble oscillation dynamics to measure the local, high-frequency viscosity of the material. We then use acoustic pressure gradients to induce bubble translation and examine the elastic part of the response of the material below yielding. We find that, at moderate pressure amplitude, the additional stresses applied by volumetric oscillations and acoustic radiation forces do not lead to any detectable irreversible bubble motion. At high pressure amplitude, we observe non-spherical shape oscillations that result in erratic bubble motion. The critical pressures we observe differ from the predictions of a recent model of shape oscillations in soft solids. Based on our findings, we discuss possible reasons for the lack of bubble release in Carbopol and suggest other systems in which ultrasound-assisted bubble rise may be observed. This journal is @en