NK

Nickolay A. Krotkov

info

Please Note

4 records found

Journal article (2026) - Robert J.D. Spurr, Matt Christi, Nickolay A. Krotkov, Won Ei Choi, Simon Carn, Can Li, Natalya Kramarova, David Haffner, J. Pepijn Veefkind, More authors...
On 15 January 2022, a highly explosive eruption of the submarine Hunga volcano (Kingdom of Tonga) generated the largest stratospheric hydration event ever observed and the largest aerosol perturbation since the 1991 Pinatubo eruption. Here, we develop a novel method for satellite retrieval of stratospheric aerosol optical depth (AOD) and layer peak height (zp) using solar backscattered ultraviolet (BUV) radiation; this is made possible by the exceptional mid-stratospheric altitude of the Hunga aerosols. We analyze BUV observations of the Hunga stratospheric aerosol cloud on 17 January 2022 (47 h after the eruption), using BUV band 1 measurements from the TROPOspheric Monitoring Instrument (TROPOMI) on board the ESA/Copernicus Sentinel-5 precursor (S5P) satellite, and the Ozone Mapping and Profiling Suite- Nadir Profiler (OMPS-NP) on board the National Oceanic and Atmospheric Administration (NOAA)-20 satellite. We retrieve AOD and zp by fitting hyperspectral BUV radiance ratios in a narrow spectral window restricted to 289–296 nm, chosen in order to reduce interference from tropospheric clouds while highly sensitive to stratospheric aerosols located above ozone peak altitude. The retrieval employs radiative transfer calculations from the Vector Linearized Discrete Ordinate Radiative Transfer (VLIDORT) forward model. We assume a single Hunga aerosol layer composed of polydisperse sulfuric acid spherical particles embedded in a Rayleigh atmosphere with a known ozone profile. The ozone profile is supplied from a version of the Modern-Era Retrospective analysis for Research and Applications, version 2 (MERRA-2) Stratospheric Composition Reanalysis of the Microwave Limb Sounder (MLS) on board NASA Earth Observing System-chemistry (EOS Aura) satellite-produced by NASA's Global Modeling and Assimilation Office using a stratospheric chemistry model and MERRA-2 meteorology. We also include a sulfur dioxide SO2 layer, which coincides spatially with the retrieved aerosol vertical profile, and with the total loading normalized to the stratospheric SO2 vertical column density from the operational TROPOMI SO2 product. We validate our AOD retrievals against ground-based AErosol RObotic NETwork (AERONET) direct-sun AOD measurements, and zp retrievals against Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) overpasses using Lagrangian trajectory modeling. We estimate the total Hunga stratospheric wet aerosol mass (sulfuric acid solution droplets, including water uptake) to be Maer∼0.5±0.05 Tg. This value is consistent with our previous BUV estimates of Hunga SO2 emissions (∼ 0.4–0.5 Tg SO2) and rapid conversion of SO2 to sulfate aerosol. Based on these BUV retrievals we can also estimate the sulfuric acid (H2SO4) mass fraction w∼0.4 and H2 SO4/H2O solution density: ρ∼1.34 g cm−3. These new values represent an extreme departure from the stratospheric background sulfate aerosol (Junge layer), which is typified by values of w∼0.75 and ρ∼1.7 g cm−3 supported by decades of observations of the lower stratosphere during both quiescent and volcanically impacted periods. The new low values, inferred from BUV observations and backed up by microphysical modeling, are a result of the uniquely water-rich conditions in the early Hunga plume. Relative humidity in the plume, as modeled by the NASA Goddard Earth Observing System Chemistry-Climate Model with the Community Aerosol and Radiation Model for Atmospheres (CARMA), reached values as high as 60 %, compared to background values closer to 1 %. These findings are unique in the long-term observational record of the stratosphere; similar relative humidities only otherwise occur in overshooting clouds or cold winter hemisphere vortices. ...
Journal article (2022) - Matthew J. Cooper, Randall V. Martin, Melanie S. Hammer, Pieternel F. Levelt, Pepijn Veefkind, Lok N. Lamsal, Nickolay A. Krotkov, Jeffrey R. Brook, Chris A. McLinden
Nitrogen dioxide (NO2) is an important contributor to air pollution and can adversely affect human health1–9. A decrease in NO2 concentrations has been reported as a result of lockdown measures to reduce the spread of COVID-1910–20. Questions remain, however, regarding the relationship of satellite-derived atmospheric column NO2 data with health-relevant ambient ground-level concentrations, and the representativeness of limited ground-based monitoring data for global assessment. Here we derive spatially resolved, global ground-level NO2 concentrations from NO2 column densities observed by the TROPOMI satellite instrument at sufficiently fine resolution (approximately one kilometre) to allow assessment of individual cities during COVID-19 lockdowns in 2020 compared to 2019. We apply these estimates to quantify NO2 changes in more than 200 cities, including 65 cities without available ground monitoring, largely in lower-income regions. Mean country-level population-weighted NO2 concentrations are 29% ± 3% lower in countries with strict lockdown conditions than in those without. Relative to long-term trends, NO2 decreases during COVID-19 lockdowns exceed recent Ozone Monitoring Instrument (OMI)-derived year-to-year decreases from emission controls, comparable to 15 ± 4 years of reductions globally. Our case studies indicate that the sensitivity of NO2 to lockdowns varies by country and emissions sector, demonstrating the critical need for spatially resolved observational information provided by these satellite-derived surface concentration estimates. ...

Overview of 14 years in space

Review (2018) - Pieternel F. Levelt, Joanna Joiner, Chris McLinden, Vitali Fioletov, Simon Carn, Jos De Laat, Matthew Deland, Sergey Marchenko, Richard McPeters, Jerald Ziemke, Dejian Fu, Xiong Liu, Johanna Tamminen, Kenneth Pickering, Arnoud Apituley, Gonzalo González Abad, Antti Arola, Folkert Boersma, Christopher Chan Miller, Kelly Chance, Martin De Graaf, Janne Hakkarainen, Seppo Hassinen, J. Pepijn Veefkind, Iolanda Ialongo, Quintus Kleipool, Nickolay Krotkov, Can Li, Lok Lamsal, Paul Newman, Caroline Nowlan, Raid Suleiman, Lieuwe Gijsbert Tilstra, Omar Torres, Pawan K. Bhartia, Huiqun Wang, Krzysztof Wargan, Deborah C.Stein Zweers, Bryan N. Duncan, David G. Streets, Henk Eskes, Ronald A. Van Der
This overview paper highlights the successes of the Ozone Monitoring Instrument (OMI) on board the Aura satellite spanning a period of nearly 14 years. Data from OMI has been used in a wide range of applications and research resulting in many new findings. Due to its unprecedented spatial resolution, in combination with daily global coverage, OMI plays a unique role in measuring trace gases important for the ozone layer, air quality, and climate change. With the operational very fast delivery (VFD; direct readout) and near real-time (NRT) availability of the data, OMI also plays an important role in the development of operational services in the atmospheric chemistry domain. ...
Journal article (2016) - Nickolay A. Krotkov, Chris A. McLinden, K. Folkert Boersma, J.P. Veefkind, Pieternel F. Levelt, Vitali E. Fioletov, Russell R. Dickerson, Hao He, Zifeng Lu, David G. Streets, Can Li, Lok N. Lamsal, Edward A. Celarier, Sergey V. Marchenko, William H. Swartz, Eric J. Bucsela, Joanna Joiner, Bryan N. Duncan
The Ozone Monitoring Instrument (OMI) onboard NASA's Aura satellite has been providing global observations of the ozone layer and key atmospheric pollutant gases, such as nitrogen dioxide (NO2) and sulfur dioxide (SO2), since October 2004. The data products from the same instrument provide consistent spatial and temporal coverage and permit the study of anthropogenic and natural emissions on local-to-global scales. In this paper, we examine changes in SO2 and NO2 over some of the world's most polluted industrialized regions during the first decade of OMI observations. In terms of regional pollution changes, we see both upward and downward trends, sometimes in opposite directions for NO2 and SO2, for different study areas. The trends are, for the most part, associated with economic and/or technological changes in energy use, as well as regional regulatory policies. Over the eastern US, both NO2 and SO2 levels decreased dramatically from 2005 to 2015, by more than 40 and 80ĝ€%, respectively, as a result of both technological improvements and stricter regulations of emissions. OMI confirmed large reductions in SO2 over eastern Europe's largest coal-fired power plants after installation of flue gas desulfurization devices. The North China Plain has the world's most severe SO2 pollution, but a decreasing trend has been observed since 2011, with about a 50ĝ€% reduction in 2012–2015, due to an economic slowdown and government efforts to restrain emissions from the power and industrial sectors. In contrast, India's SO2 and NO2 levels from coal power plants and smelters are growing at a fast pace, increasing by more than 100 and 50ĝ€%, respectively, from 2005 to 2015. Several SO2 hot spots observed over the Persian Gulf are probably related to oil and gas operations and indicate a possible underestimation of emissions from these sources in bottom-up emission inventories. Overall, OMI observations have proved valuable in documenting rapid changes in air quality over different parts of the world during last decade. The baseline established during the first 11 years of OMI is indispensable for the interpretation of air quality measurements from current and future satellite atmospheric composition missions. ...