C.S. Boeije
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7 records found
1
REFLECT DELIVERABLE D2.2
Report on gas solubility and degassing kinetic (type C)
Foam is used in gas-injection EOR processes to reduce the mobility of gas, resulting in greater volumetric sweep. SAG (Surfactant Alternating Gas) is a preferred method of injection as it results in greater injectivity in the field, but designing a successful process requires knowledge of foaming performance at very high foam qualities (gas fractional flows). Here the use of foam in low-permeability (∼1 mD) Indiana Limestone cores for SAG foam applications is studied. Coreflood experiments were performed for a range of foam qualities at high pressure (100 bar), elevated temperature (55 °C), high salinity (200,000 ppm) and in the presence of crude oil. The effectiveness of the foam was studied by differential pressure measurements along the core. Foam was still able to form under these stringent conditions, but it was a relatively weak foam (i.e. its ability to reduce gas mobility is modest). For one surfactant formulation, further analysis of the experimental results show that the foam would be able to maintain mobility control over the displaced phase, thus providing a stable displacement front, and that it can be used in a SAG foam process in these formations. For a second formulation the non-monotonic nature of the fractional-flow data requires further investigation before scale-up to the field. In addition, further coreflood experiments were carried out using heterogeneous, vuggy Edwards White cores with even lower permeability (∼0.5 mD). These experiments were performed to determine whether foaming is possible in heterogeneous media and especially to investigate the effects of disconnected vugs on the foaming performance. CT scans were taken during the period of foam injection to determine saturation profiles within the core. Foam was able to form inside these cores, but inside the vugs segregation was observed with liquid pockets visible in the bottom of the vugs and gas in the remainder. This segregation was only a local effect though, confined to the vug itself, and foam was able to persist in the rest of the core.
The bulk-foam tests screened out most of the considered surfactants. Out of 31 surfactants tested, 26 precipitated in the highest-salinity brine (200,000 ppm). Also, the presence of crude oil resulted in foam collapse for most surfactants in the bulk tests. Surfactants that retained some foam stability in the presence of oil were carried forward to the porous-media tests. In our study, qualitative foam stability inferred from the bulk-foam-stability tests correlated well with the MRF in the water-wet bead packs. We found large variations in MRF comparing different surfactants; some have MRFs on the order of 10 and others are as high as 1,000. For all investigated surfactants, the presence of crude oil reduced MRF, but for some mobility reduction was still significant. The bulk-foam tests showed similar results, with foam retaining some stability even in the presence of oil for the surfactants that were analyzed in both bulk form and in porous media. Oil-wetness was found to have a detrimental effect on foam strength: Values of MRF were approximately one order of magnitude lower than those measured in the water-wet porous media. However, the decrease in MRF was not the same for all surfactants. The best-performing surfactant in the oil-wet pack was not the same as the best performer in the water-wet pack, proving the value of these additional tests.
The goal of the protocol is to obtain a method for rapid testing the foaming performance and stability of a range of surfactants under conditions that are as realistic as possible. The most-promising surfactant(s) identified by use of this protocol are then selected to be evaluated further in long consolidated cores.
...
The bulk-foam tests screened out most of the considered surfactants. Out of 31 surfactants tested, 26 precipitated in the highest-salinity brine (200,000 ppm). Also, the presence of crude oil resulted in foam collapse for most surfactants in the bulk tests. Surfactants that retained some foam stability in the presence of oil were carried forward to the porous-media tests. In our study, qualitative foam stability inferred from the bulk-foam-stability tests correlated well with the MRF in the water-wet bead packs. We found large variations in MRF comparing different surfactants; some have MRFs on the order of 10 and others are as high as 1,000. For all investigated surfactants, the presence of crude oil reduced MRF, but for some mobility reduction was still significant. The bulk-foam tests showed similar results, with foam retaining some stability even in the presence of oil for the surfactants that were analyzed in both bulk form and in porous media. Oil-wetness was found to have a detrimental effect on foam strength: Values of MRF were approximately one order of magnitude lower than those measured in the water-wet porous media. However, the decrease in MRF was not the same for all surfactants. The best-performing surfactant in the oil-wet pack was not the same as the best performer in the water-wet pack, proving the value of these additional tests.
The goal of the protocol is to obtain a method for rapid testing the foaming performance and stability of a range of surfactants under conditions that are as realistic as possible. The most-promising surfactant(s) identified by use of this protocol are then selected to be evaluated further in long consolidated cores.
Foam is used in gas-injection EOR processes to reduce the mobility of gas, resulting in greater volumetric sweep. SAG (Surfactant Alternating Gas) is a preferred method of injection as it results in greater injectivity in the field, but designing a successful process requires knowledge of foaming performance at very high foam qualities (gas fractional flows). Here the use of foam in low-permeability (~1 mD) Indiana Limestone cores for SAG foam applications is studied. Coreflood experiments were performed for a range of foam qualities at high pressure (100 bar), elevated temperature (55°C), high salinity (200,000 ppm) and in the presence of crude oil. The effectiveness of the foam was studied by differential pressure measurements along the core. Foam was still able to form under these stringent conditions, but it was a relatively weak foam (i.e. its ability to reduce gas mobility is modest). For one surfactant formulation, further analysis of the experimental results show that the foam would be able to maintain mobility control over the displaced phase, thus providing a stable displacement front, and that it can be used in a SAG foam process in these formations. For a second formulation the non-monotonic nature of the fractionalflow data require further investigation before scale-up to the field. In addition, further coreflood experiments were carried out using heterogeneous, vuggy Edwards White cores with even lower permeability (~0.5 mD). These experiments were performed to determine whether foaming is possible in heterogeneous media and especially to investigate the effects of disconnected vugs on the foaming performance. CT scans were taken during the period of foam injection to determine saturation profiles within the core. Foam was able to form inside these cores, but inside the vugs foam segregation was observed with liquid pockets visible in the bottom of the vugs and gas in the remainder. This segregation was only a local effect though, confined to the vug itself, and foam was able to persist in the rest of the core. ...
Foam is used in gas-injection EOR processes to reduce the mobility of gas, resulting in greater volumetric sweep. SAG (Surfactant Alternating Gas) is a preferred method of injection as it results in greater injectivity in the field, but designing a successful process requires knowledge of foaming performance at very high foam qualities (gas fractional flows). Here the use of foam in low-permeability (~1 mD) Indiana Limestone cores for SAG foam applications is studied. Coreflood experiments were performed for a range of foam qualities at high pressure (100 bar), elevated temperature (55°C), high salinity (200,000 ppm) and in the presence of crude oil. The effectiveness of the foam was studied by differential pressure measurements along the core. Foam was still able to form under these stringent conditions, but it was a relatively weak foam (i.e. its ability to reduce gas mobility is modest). For one surfactant formulation, further analysis of the experimental results show that the foam would be able to maintain mobility control over the displaced phase, thus providing a stable displacement front, and that it can be used in a SAG foam process in these formations. For a second formulation the non-monotonic nature of the fractionalflow data require further investigation before scale-up to the field. In addition, further coreflood experiments were carried out using heterogeneous, vuggy Edwards White cores with even lower permeability (~0.5 mD). These experiments were performed to determine whether foaming is possible in heterogeneous media and especially to investigate the effects of disconnected vugs on the foaming performance. CT scans were taken during the period of foam injection to determine saturation profiles within the core. Foam was able to form inside these cores, but inside the vugs foam segregation was observed with liquid pockets visible in the bottom of the vugs and gas in the remainder. This segregation was only a local effect though, confined to the vug itself, and foam was able to persist in the rest of the core.