This study reports the synthesis of a nanohybrid material composed of poly(2-methylaniline) (P(2MA)) and iron oxide (Fe2O3) as electrodes for supercapacitors using a simple and cost-effective method. Various characterization techniques were employed to analyze the samples. The results revealed that the Fe2O3/P(2MA) nanohybrid exhibits nanofiber structures, while pure P(2MA) displays a porous hollow sphere morphology. Furthermore, the analysis confirmed the effective dispersion of Fe2O3 nanoparticles within the polymer matrix. The electrochemical properties of the Fe2O3/P(2MA) nanohybrid were found to surpass those of pure P(2MA) in both NaCl and HCl electrolytes. Notably, the nanohybrid demonstrated longer discharge times and higher oxidation/reduction currents in HCl than NaCl. The gravimetric and areal capacitances were measured at 998.4 F g−1 and 1497.6 mF cm−2 in 0.5 M HCl at a current density of 0.6 A g−1. Furthermore, the nanohybrid retained 99.9% of its initial specific capacitance after 2,000 cycles. These findings underscore the significant potential of the Fe2O3/P(2MA) nanohybrid as a high-performance supercapacitor electrode for energy storage applications.

Lead-free halide perovskite, kesterite, and delafossite semiconductors were integrated into a multilayer ternary heterostructure (Cs₂ SnCl₆ /Cu₂ ZnSnS₄ /CuFeO₂) to enable direct solar-driven hydrogen production from sewage water. X-ray photoelectron spectroscopy confirms the expected elemental composition and oxidation states, while X-ray diffraction verifies the successful incorporation of all three layers with well-defined crystallinity. Optical measurements reveal a systematic narrowing of the effective band gap, decreasing from 1.73 eV for CuFeO₂ to 1.50 eV for the Cu₂ ZnSnS₄ /CuFeO₂ bilayer and further to 1.12 eV for the complete Cs₂ SnCl₆ /Cu₂ ZnSnS₄ /CuFeO₂ stack. The multilayered architecture enabled effective charge separation and transport, delivering a photocurrent density of −24.0 mA cm-2, approximately 77 times higher than the dark current density. The incident photon-to-current efficiency reaches 77%. These results demonstrate strong photoresponsivity and confirm the suitability of the multilayer heterojunction for efficient solar-driven hydrogen production. The extracted thermodynamic parameters (ΔH* = 3.452 kJ mol⁻¹ and ΔS* = 9.644 J mol⁻¹ K⁻¹) indicate a low activation barrier for interfacial charge transfer, suggesting that the system effectively couples photonic and thermal contributions to enhance hydrogen-evolution kinetics. Collectively, these findings establish the all-lead-free Cs₂ SnCl₆ /Cu₂ ZnSnS₄ /CuFeO₂ heterostructure as a highly efficient photoelectrode for solar-to-hydrogen conversion in complex wastewater environments. Demonstrating hydrogen evolution directly from sewage water further highlights the dual functionality of this architecture for simultaneous wastewater valorization and sustainable fuel production.