Fractured and karstified carbonate units are key exploration targets for the hydrocarbon industry as they represent important reservoirs. Furthermore, large water reserves and geothermal systems are hosted in carbonate aquifers. This paper documents the relationships between stratigraphy, structural patterns, silicification, and the spatial-morphological organization of a 3D multistorey cave system developed in a Neoproterozoic mixed carbonate-siliciclastic sequence. We found that the combination of lithology, silicification, fracture patterns (controlled by lithostratigraphic variability), and petrophysical properties control the formation of high or low permeability zones; their distribution was fundamental for the spatial organization of dissolution and the compartmentalization of the resulting conduit system in different speleogenetic storeys. We propose a deep-seated hydrothermal origin for the fluids involved in the main phases of karst formation. Warm and alkaline hydrothermal fluids caused silica dissolution, followed by chalcedony and quartz reprecipitation in pore space and fractures. Rising fluids concentrated along through-going vertical fracture zones in the lower storey, whereas sub-horizontal bedding-parallel fluid flow was focused on sedimentary packages containing highly silicified dolostones (SiO₂>80 wt%) characterized by high permeability. The Calixto Cave is an enlightening example for the complex speleogenetic history affecting a mixed carbonate-siliciclastic succession where the combined effect of silicification and hydrothermal karst dissolution can potentially generate high-quality reservoirs.

Caves developed in carbonate units have a significant role in fluid flow, but most of these subsurface voids are below seismic resolution. We concentrated our study on four caves to determine the roles of fractures and folds in the development of karst conduits that may form flow pathways in carbonate reservoirs. We performed structural field investigations, petrographic analyses, and geometric characterization using Light Detection and Ranging (LIDAR) for caves in Neoproterozoic carbonates of the Salitre Formation, central part of the São Francisco Craton, Brazil. We found that the conduit shape, usually with an ellipsoidal cross-section, reflects the tectonic features and textural variations. Carbonate layers containing pyrite and low detritic mineral contents are generally karstified and appear to act as favorable flow pathways. Our results indicate that the development of the karst system is related to fracture corridors formed along parallel and orthogonal sets of fold hinges, which provide preferential pathways for fluid flow and contribute to the development of super-K zones. This study provides insights into the prediction of subseismic-scale voids in carbonate reservoirs, with direct application for the hydrocarbon and hydrogeology flow and storage.

The hypogenic caves developed in carbonate units have a significant structural control but most of their features are not detect by conventional methods due to their size below seismic resolution. This contribution focuses on the structural, petrographic and geometric characterization of karst conduits in Neoproterozoic carbonates of the Salitre Formation, central part of São Francisco Craton, Brazil. We address the influence of fractures and folds on the development of karst conduits through field and laboratory analysis and the application of Light Detection Ranging to characterize cave/conduit geometry. The preliminary results indicate that the process of karstification are intensified in fractures corridors developed along fold hinges, which create fluid flow corridors in carbonate units and may change petrophysical reservoir properties.

The carbonate rocks exposed in the Irecê (Brazil) are pervasively affected by hydrothermal silicification and dolomitization. These mineralizing events drastically changed the original petrophysical properties of the host rock. In order to understand the role played by deformation mechanisms and tectonic evolution of these carbonates on the ingression of the mineralizing fluids, we focused our study on the mineralogical, petrographic, stratigraphic, structural and geochemical characterization of the faulted Neoproterozoic carbonates of the Salitre Formation, central Brazil. In this contribution, we present the first results of a combined outcrop- to micro-scale investigation of the structural evolution of the fracture network responsible for hydrothermal silicification and dolomitization processes.