Electrodes are used to measure a potential difference between two points. In geophysical and geotechnical applications they are often in the form of non-polarizable porous-pot electrodes. Here we describe the design, construction, and testing of modular and refillable electrodes, which facilitates repair as the electrodes degrade over time. We use a chemical composition based on a metal in contact with an over-saturated electrolyte that consists of a salt of that metal and an auxiliary salt. We compare characteristics when the electrolyte is stabilized in a clay or not, and with various states of ceramic porous plugs and two types of wood plugs. Next, we assess the long-term stability (more than 1 month), noise (periods of 1 s to 1 hr), and temperature sensitivity of different types of electrodes. Electrodes with an electrolyte and clay formula showed lower noise (0.2–0.4 μV at periods of 1–120 s), greater long-term stability (0.05–0.5 mV/month of smooth drift), and greater consistency between samples measured than those with no clay (noise and drift values up to four times larger). The effects from different porous plugs were negligible, with similar results for ceramic and wood types. The temperature sensitivity of the electric potential was assessed, from −3 to 35°C. All electrodes showed a temperature sensitivity of about −30 μV/°C. This is considered very low compared to some commercially available electrodes. Finally, continuous long-term laboratory and field measurements of the potential highlight the application of the new electrodes.@en

We carried out long-term measurements of the electric potential in the laboratory and in the field and assessed the stability and temperature sensitivity of the recordings.

In the field, a robust design for long-term telluric recordings including a redundant parallel dipole so that consecutive stable time windows are more likely to be recorded was implemented in the Sauerland region of Germany (more than three months). Field testing is complicated by the fact that the system is no longer in isolation. However, the stability of the electric potential measured in the laboratory was a reasonable predictor of the stability of electric potential measured in the field. Nevertheless, instabilities in the form of spikes in the potential, steps, and spontaneous jumps (on the order of 1 mV) of unknown origin were observed.

The field measurements included a temperature-logging device. The temperature was monitored at two locations: a) the bottom-hole temperature at a depth of 80 cm below the surface, where the electrode was planted, and b) the top-hole temperature at a depth of 5 cm below the surface. The recorded temperatures in the electrode hole can be compared to the air temperature (as recorded in the nearby village). The results clearly show that planting the electrode deeper avoids the daily variations of temperature, which, in this case, were appreciable (up to 7°C), and which can affect the electric potential recordings. The bottom-hole temperature variation follows the long-term seasonal trend (e.g., 1–2°C/10 days), but is insensitive to short-term variations. Furthermore, installing electrodes at such depths can insulate them and avoid problems associated with the temperature going below the freezing point.
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