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S. Peelman
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The rare earth elements (REEs) are a material group that is becoming increasingly important in modern day technologies, with applications in electronics (e.g. FeNdB magnets and luminescent phosphors), chemical industry (e.g. REE catalysts), energy industry (e.g. NiMH batteries and windmills) and medicine (e.g. Gd MRI contrast fluid). Considering the importance of REEs, a steady and secure supply is essential. However, the European Union does not have any domestic production of these elements and is reliant on import from China to meet its REE demand. With the volatility of the REE market and potential Chinese export restrictions, the EU has begun exploring secondary low-grade resources to mitigate a potential shortage of REEs.
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The rare earth elements (REEs) are a material group that is becoming increasingly important in modern day technologies, with applications in electronics (e.g. FeNdB magnets and luminescent phosphors), chemical industry (e.g. REE catalysts), energy industry (e.g. NiMH batteries and windmills) and medicine (e.g. Gd MRI contrast fluid). Considering the importance of REEs, a steady and secure supply is essential. However, the European Union does not have any domestic production of these elements and is reliant on import from China to meet its REE demand. With the volatility of the REE market and potential Chinese export restrictions, the EU has begun exploring secondary low-grade resources to mitigate a potential shortage of REEs.
Neodymium is a critical element used in many high-tech applications. However, despite this, the EU is entirely dependent on China for its Nd supply. This has driven the EU to develop recycling strategies to recover its Nd from end-of-life (EoL) products and wastes, and establish a domestic supply. This paper proposes a process to recycle Nd from NdFeB magnet particles present in the ferrous fraction of shredded “Waste Electrical and Electronic Equipment” (WEEE), after physical upgrading. This WEEE fraction represents a waste stream that has not been previously considered a source of Nd. A three-step process was developed. First, the upgraded ferrous WEEE fraction is oxidized by means of water corrosion. Second, the oxidized WEEE is leached with diluted H2SO4 to selectively extract Nd and other nonferrous elements. And finally, the leach liquor is treated with Na2SO4 to precipitate the Nd as its double sulfate (Nd, Na)(SO4)2. The oxidation process oxidizes 93% of the metallic iron to Fe(OH)3, leaving 7% of the iron unoxidized. The leaching process dissolves between 70 and 99% of the Nd, depending on the temperature and liquid/solid ratio (L/S); this is accompanied by an iron coextraction between 9 and 20%. The precipitation recovers 92% of the leached Nd. The purity of the obtained precipitates is dependent on the pH at which the precipitation takes place. A pH below 0.5 is required to prevent Fe contamination, and a pH below 0 reduces the Ca contamination to below 1 wt%. The developed process provides an effective and low-cost method to recycle Nd from a shredded WEEE stream with an overall Nd recovery of over 90%.
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Neodymium is a critical element used in many high-tech applications. However, despite this, the EU is entirely dependent on China for its Nd supply. This has driven the EU to develop recycling strategies to recover its Nd from end-of-life (EoL) products and wastes, and establish a domestic supply. This paper proposes a process to recycle Nd from NdFeB magnet particles present in the ferrous fraction of shredded “Waste Electrical and Electronic Equipment” (WEEE), after physical upgrading. This WEEE fraction represents a waste stream that has not been previously considered a source of Nd. A three-step process was developed. First, the upgraded ferrous WEEE fraction is oxidized by means of water corrosion. Second, the oxidized WEEE is leached with diluted H2SO4 to selectively extract Nd and other nonferrous elements. And finally, the leach liquor is treated with Na2SO4 to precipitate the Nd as its double sulfate (Nd, Na)(SO4)2. The oxidation process oxidizes 93% of the metallic iron to Fe(OH)3, leaving 7% of the iron unoxidized. The leaching process dissolves between 70 and 99% of the Nd, depending on the temperature and liquid/solid ratio (L/S); this is accompanied by an iron coextraction between 9 and 20%. The precipitation recovers 92% of the leached Nd. The purity of the obtained precipitates is dependent on the pH at which the precipitation takes place. A pH below 0.5 is required to prevent Fe contamination, and a pH below 0 reduces the Ca contamination to below 1 wt%. The developed process provides an effective and low-cost method to recycle Nd from a shredded WEEE stream with an overall Nd recovery of over 90%.
The present study proposes three distinct processes to recycle rare earth elements (REE) from two low-grade secondary resources: REE-containing mine tailings and ferrous scrap from shredded waste of electrical and electronic equipment (WEEE). The first developed process extracts both REE and phosphorus from the apatite mineral contained within the mine tailings by way of acidic leaching, followed by cryogenic crystallization and solvent extraction to purify both the REE and P products. This process successfully recovers 70–100% of the REE from the apatite and over 99% of its P. The second developed process is a low-cost, efficient method to recover Nd from the ferrous scrap of shredded WEEE. This is achieved by a water corrosion step followed by acidic leaching and precipitation. The overall Nd recovery of this approach is over 90%. The final process recovers both the Nd and the Fe from the shredded WEEE scrap. This is done by smelting the shredded WEEE scrap prior to leaching to produce metallic Fe- and a Nd-rich slag. The recovery rates of both Nd and Fe are over 90% and minimal waste is produced; however, the energy consumption is considerable.
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The present study proposes three distinct processes to recycle rare earth elements (REE) from two low-grade secondary resources: REE-containing mine tailings and ferrous scrap from shredded waste of electrical and electronic equipment (WEEE). The first developed process extracts both REE and phosphorus from the apatite mineral contained within the mine tailings by way of acidic leaching, followed by cryogenic crystallization and solvent extraction to purify both the REE and P products. This process successfully recovers 70–100% of the REE from the apatite and over 99% of its P. The second developed process is a low-cost, efficient method to recover Nd from the ferrous scrap of shredded WEEE. This is achieved by a water corrosion step followed by acidic leaching and precipitation. The overall Nd recovery of this approach is over 90%. The final process recovers both the Nd and the Fe from the shredded WEEE scrap. This is done by smelting the shredded WEEE scrap prior to leaching to produce metallic Fe- and a Nd-rich slag. The recovery rates of both Nd and Fe are over 90% and minimal waste is produced; however, the energy consumption is considerable.
The rare earth elements (REEs) present in the Kiruna iron ore mine tailings are being considered as a new REE resource for the EU. These tailings, after beneficiation, contain approximately 5000 ppm of rare earths, concentrated in apatite and monazite minerals. To economically extract the REEs from these tailings the phosphorous contained within the apatite must also be extracted and the waste production of the process should be minimal. To achieve the extraction of REEs and phosphorous HCl and HNO3 were investigated as possible leaching agents. Based on the results a leaching process using HNO3 is proposed. This process produces H3PO4 from the apatite while simultaneously dissolving the REEs. The resulting leach liquor is then cooled to remove the unwanted Ca as Ca(NO3)2. Analysis of the leach liquor reveals extraction ratios of between 75% and 100% for the heavy REE (e.g. Y, Eu, Dy, …) and below 40% from the light REEs (i.e. Ce, La). Full phosphorous extraction was also achieved.
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The rare earth elements (REEs) present in the Kiruna iron ore mine tailings are being considered as a new REE resource for the EU. These tailings, after beneficiation, contain approximately 5000 ppm of rare earths, concentrated in apatite and monazite minerals. To economically extract the REEs from these tailings the phosphorous contained within the apatite must also be extracted and the waste production of the process should be minimal. To achieve the extraction of REEs and phosphorous HCl and HNO3 were investigated as possible leaching agents. Based on the results a leaching process using HNO3 is proposed. This process produces H3PO4 from the apatite while simultaneously dissolving the REEs. The resulting leach liquor is then cooled to remove the unwanted Ca as Ca(NO3)2. Analysis of the leach liquor reveals extraction ratios of between 75% and 100% for the heavy REE (e.g. Y, Eu, Dy, …) and below 40% from the light REEs (i.e. Ce, La). Full phosphorous extraction was also achieved.