Proton exchange membrane fuel cells offer promising clean energy solutions for various applications. However, their performance relies heavily on the properties of the microporous layer, which plays a crucial role in transporting and distributing the components in the fuel cell. To date, the potential for optimising the microporous layer material structural parameters to enhance the fuel cell performance remains largely unexplored. This study aims to fill this research gap by conducting a comprehensive investigation of the effects of different microporous layer material structural parameters on the heat and mass transfer in the membrane electrode assembly. MATLAB was used for optimising the performance of the fuel cell components. The results show that increasing the microporous layer thickness from 5 to 50 μm significantly affects the species transport, leading to a substantial reduction in the molar fraction of H₂ and O₂ at the electrochemical reaction sites. Furthermore, the distribution of the liquid water saturation inside the fuel cell is influenced by the porosity and permeability of the microporous layer. By increasing the porosity from 0.3 to 0.6, the liquid water saturation at the interface of the catalyst layer and microporous layer decreases by 0.52 % and 1.12 % at output voltages of 0.5 V and 0.7 V, respectively. This reduction enhances the efficiency of internal water transport. Moreover, reducing the permeability of the microporous layer from 2 × 10^-12 to 1 × 10^-13 at 0.5 V and 0.7 V leads to an increase in liquid water saturation at the interface of the proton exchange membrane and the catalyst layer by 1.49 % and 0.74 %, respectively, causing hindrance to the transport of internal liquid water. This study provides valuable insights into the interplay between the properties of the microporous layer material properties and heat and mass transfer characteristics in proton exchange membrane fuel cell.

In response to the growing global demand for clean and sustainable energy solutions, proton exchange membrane fuel cells (PEMFCs) have emerged as vital components in diverse decarbonization strategies. Despite their increasing importance, a comprehensive synthesis of recent advancements, challenges, and future prospects in thermal and water management within this domain remains notably scarce. This paper aims to bridge this gap by conducting a meticulous literature review focused on thermal and water management in PEMFCs. Primarily, this study encapsulates the underlying mechanisms governing thermal and water generation in PEMFCs, intricately analyzing thermal and water generation analyses. Secondly, a multifaceted exploration of thermal and water transfer mechanisms, alongside their pivotal influencing factors, is presented. Furthermore, the discourse delves into sophisticated strategies for refining water and thermal management in PEMFCs. As well as delving into the complexities of high-power heat dissipation and water balance, especially water management for cold start and high temperature operating conditions. The culmination of this investigation yields valuable insights into the intricate dynamics of thermal and water management within PEMFCs, thereby culminating in forward-looking recommendations for future research trajectories. These findings not only offer scholars a vantage point to discern emerging research frontiers and trends but also extend theoretical precepts and reference points for technology innovators and product developers.