V. Bliznuk
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1
The microstructure and mechanical properties of an Fe-0.24C-1.4Mn-1.4Si steel were investigated after combining ultrafast heating (UFH) at a heating rate of 500 °C/s followed by fast cooling to room temperature (DQ) or quenching and partitioning processes (Q&P). Two peak temperatures were studied, annealing into the intercritical range and above the AC3 temperature. After ultrafast heating and quenching, the resulting microstructures revealed that intercritical annealing led to the formation of a banded ferritic-martensitic microstructure. On the other hand, heating above the intercritical range led to an even distribution of allotriomorphic ferrite grains upon fast cooling and a complex phase microstructure, consisting mainly of martensite, was produced. Q&P steel grades exhibit an enhanced mechanical behavior compared to their DQ counterparts, where yield strength, uniform elongation, and total elongation increased after partitioning at 400 °C. The ultimate tensile strength of the Q&P steels decreased compared to the DQ steels annealed at the same peak temperature. However, the final strength-ductility balance of the studied Q&P steels was superior to the DQ steel grades. Moreover, considerable strength and improved ductility were obtained through the combination of peak annealing above the AC3 temperature followed by Q&P. These results are attributed to an interplay between a sustainable TRIP effect and effective strain-stress partitioning among the microconstituents resulted after the Q&P process.
Lath martensite is important in industry because it is the key strengthening component in many advanced high strength steels. The study of crystallography and chemistry of lath martensite is extensive in the literature, however, mostly based on fully martensitic steels. In this work, lath martensite in dual phase steels is investigated with a focus on the substructure identification of the martensite islands and microstructural bands using electron backscattered diffraction, and on the influence of the accompanied tempering process during industrial coating process on the distribution of alloying elements using atom probe tomography. Unlike findings for the fully martensitic steels, no martensite islands with all 24 Kurdjumov-Sachs variants have been observed. Almost all martensite islands contain only one main packet with all six variants and minor variants from the remaining three packets of the same prior austenite grain. Similarly, the martensite bands are typically composed of connected domains originating from prior austenite grains, each containing one main packets (mostly with all variants) and few separate variants. The effect of tempering at ~450 °C (due to the industrial zinc coating process) has also been investigated. The results show a strong carbon partitioning to lath boundaries and Cottrell atmospheres at dislocation core regions due to the thermal process of coating. In contrast, auto-tempering contributes to the carbon redistribution only in a limited manner. The substitutional elements are all homogenously distributed. The phase transformation process has two effects on the material: mechanically, the earlier-formed laths are larger and softer and therefore more ductile (as revealed by nanoindentation); chemically, due to the higher dislocation density inside the later-formed laths, which are generally smaller, carbon Cottrell atmospheres are predominantly observed.