Micropatterned surfaces with both hydrophilic and hydrophobic regions are relevant for a wide range of applications from fuel cells to water harvesting systems. The preferential nucleation of water on hydrophilic regions can also be used to control frost nucleation on chemically patterned surfaces. So far, this concept has been tested on brittle silicon surfaces with only a few different sizes and shapes of hydrophilic regions. In this work, the concept of controlled icing is investigated on five polymeric surfaces with different surface energies modified by micropatterning them with three types of hydrophilic polymer brushes. Frost formation and propagation on the resulting patterned surfaces with regions of varying wettability is monitored and quantified using high-resolution thermal imaging. The study proves that control over frost nucleation and propagation using regions of varying wettability can be achieved on commodity polymers. In addition to influencing the time and location of ice nucleation, the local patterning affects the freezing propagation mode and rate due to its impact on the continuity and thickness of molecular water layers (MWL). These results show that local control over the state of MWLs is key to controlling both ice nucleation and propagation of freezing events on surfaces.

The successful use of ice-binding proteins (IBPs) to develop anti-icing surfaces requires a comprehensive understanding of their working mechanism when introduced in environments distinct from the protein's natural setting. This study systematically addresses this aspect by investigating how IBPs control ice accretion when grafted onto an aluminum alloy using polyethylene glycol (PEG) linkers of various lengths and on the polymer backbone of a PEG hydrogel matrix. Freezing experiments monitored through thermal imaging reveal that the degrees of freedom of the proteins significantly influence their functionality. Specifically, we demonstrate that when the degrees of freedom of anti-freeze proteins (AFPs) are restricted by their functionalization on surfaces using short linkers or when they are present in restricted volumes in polymers, they behave as ice-nucleating proteins (INPs) promoting ice accretion. In conditions where their degrees of freedom are enhanced (long linkers, water-rich environment), AFPs effectively inhibit ice nucleation and propagation. The work underlines the relevance of protein mobility as a so far unforeseen key design factor needed to fully benefit from the potential use of natural or synthetic AFPs grafted on surfaces for cryopreservation of biological samples and the design of next-generation low-icing surfaces and coatings.

Impacting supercooled water droplets commonly cause in-flight ice accumulation on aircraft surfaces. Ice accretion can lead to dangerous situations such as disturbance of airflow around the aircraft wings, breakdown of vital antennae, or even malfunction of the engines. The adverse effects of aircraft icing could be avoided by designing passive anti-icing surfaces that either delay ice nucleation after droplet impact and/or reduce ice adhesion to promote its shedding. Among potential passive anti-icing strategies, smooth surfaces with patterned hydrophilic and hydrophobic regions have shown good potential to control local frost formation. In this study, we investigate how hydrophilic 150 µm wide stripes influence the impact and freezing of supercooled water droplets on two polymeric substrates (Polyvinylchloride and Polypropylene). In addition to varying the wettability difference between the stripes and the substrate, the distance between the stripes (1.25—10 mm) and the impact velocity of the water droplet (4.1—6.5 m/s) were varied. High-speed video analysis of the impacting droplets shows that the presence of the hydrophilic patterns can lower ice nucleation rates and direct the shape of the droplet spreading after impact. However, a low wettability difference between the substrate and the patterns can lead to the opposite scenario with higher nucleation rates.

In this work, we study the relationship between the molecular water layer (MWL) and frost freezing onset and propagation. The progression of frost has been reported to be governed by various localized icing phenomena, including interdroplet ice bridging, dry zones, and frost halos. Reports studying the state of water on surfaces have revealed the presence of a thin nanometer water layer on a range of surfaces. Regardless of further investigations that show environmental humidity, temperature, and surface energy to affect the thickness of the MWL on surfaces, the influence of the MWL on frost nucleation and propagation has not yet been previously addressed in the literature. To study the effect of the MWL on surface freezing events, a range of surface-functionalized glass substrates were prepared. In situ monitoring of freezing events with thermal imaging allowed studying the effect of surface chemistry and environmental relative humidity (RH) on the thickness and continuity of the MWL. We argue that the observed icing nucleation and propagation kinetics are directly related to the presence and continuity of the MWL, which can be manipulated by controlling the environmental humidity and surface chemistry.