Improved PECVD processed hydrogenated germanium films through temperature induced densification
Thierry De Vrijer (TU Delft - Photovoltaic Materials and Devices)
Julian E.C. van Dingen (Student TU Delft)
Paul J. Roelandschap (Student TU Delft)
Koos Roodenburg (Student TU Delft)
Arno H.M. Smets (TU Delft - Photovoltaic Materials and Devices)
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Abstract
Amorphous and nano-crystalline germanium is of potential interest for a wide range of electronic, optical, opto-electronic and photovoltaic applications. In this work the influence of deposition temperature on hydrogenated germanium (Ge:H) films was characterized, using over 200 Ge:H and over 70 SiGe:H films. The demonstrated temperature-induced densification of Ge:H films resulted in more stable films with a lower bandgap energy and dark conductivity and higher activation energy.