Bulk material properties of NaBH4

Master Thesis (2023)
Author(s)

B. Romijn (TU Delft - Mechanical Engineering)

Contributor(s)

M.C. van Benten – Mentor (TU Delft - Marine and Transport Technology)

DL Schott – Graduation committee member (TU Delft - Transport Engineering and Logistics)

J.T. Padding – Graduation committee member (TU Delft - Complex Fluid Processing)

Faculty
Mechanical Engineering
Copyright
© 2023 Bjørn Romijn
More Info
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Publication Year
2023
Language
English
Copyright
© 2023 Bjørn Romijn
Graduation Date
05-12-2023
Awarding Institution
Delft University of Technology
Programme
Mechanical Engineering | Multi-Machine Engineering
Faculty
Mechanical Engineering
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Abstract

Sodium borohydride (NaBH4) is a potential material-based hydrogen storage solution. However, a lack of information regarding its bulk material properties poses a challenge in designing storage and handling equipment. This report addresses this gap by conducting a series of tests to analyse the bulk material properties of NaBH4 powder and granules, with a specific interest in how these properties change under varying humidity conditions.
Since humidity does not have a direct effect on material properties, but moisture content does, the report first investigates the effect of humidity on moisture content in the material. The second set of experiments is then designed to determine the bulk material properties with varying moisture content, establishing a link between humidity and bulk material properties.
The findings reveal that prolonged exposure to ambient humidity negatively affects the cohesion and flowability of NaBH4. This effect is more pronounced in powdered NaBH4 compared to its granulated form. However, these adverse effects can be mitigated by storing the material in a closed environment. The study concludes by emphasizing the importance of a closed storage environment and the need for further research on NaBH4’s behaviour under a wider range of conditions for its storage and handling.

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