Charge transport through conjugated azomethine-based single molecules for optoelectronic applications
Max Koole (TU Delft - Solutions)
R Frisenda (TU Delft - QN/van der Zant Lab)
ML Petrus (Ludwig Maximilians University, TU Delft - Novel Aerospace Materials)
Mickael Perrin (TU Delft - QN/van der Zant Lab)
H. S J van der Zant (TU Delft - QN/van der Zant Lab)
Theo Dingemans (TU Delft - Novel Aerospace Materials, TU Delft - OLD ChemE/Organic Materials and Interfaces)
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Abstract
The single-molecule conductance of a 3-ring, conjugated azomethine was studied using the mechanically controlled breakjunction technique. Charge transport properties are found to be comparable to vinyl-based analogues; findings are supported with density functional calculations. The simple preparation and good transport properties make azomethine-based molecules an attractive class for use in polymer and single-molecule organic electronics.
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