Electrocatalytic Production of a Liquid Organic Hydrogen Carrier with Anodic Valorization of the Process

Review and Outlook

Review (2025)
Author(s)

Jiaqi Wang (Aalto University)

Yongdan Li (Aalto University)

Christin Hummel (Hydrogenious LOHC Technologies)

Guo Huang (Luleå University of Technology)

Xiaoyan Ji (Luleå University of Technology)

E. Demiröz (TU Delft - ChemE/Catalysis Engineering)

A. Urakawa (TU Delft - ChemE/Catalysis Engineering)

Siyuan Huang (Technische Universität München)

Ruixue Zhao (Technische Universität München)

Johannes A. Lercher (Technische Universität München)

Paola Lanzafame (University of Messina)

Georgia Papanikolaou (University of Messina)

Gabriele Centi (University of Messina)

Research Group
ChemE/Catalysis Engineering
DOI related publication
https://doi.org/10.1021/acs.energyfuels.4c04644
More Info
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Publication Year
2025
Language
English
Research Group
ChemE/Catalysis Engineering
Issue number
1
Volume number
39
Pages (from-to)
132-165
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Abstract

Green hydrogen plays a crucial role in decarbonization and the future of low-carbon society. Still, its transport/distribution and cost of production, mainly realized by electrolysis, are major hurdles. Liquid H2 carriers reduce transport/distribution costs but add further expenses for their production. To address this challenge, we proposed a novel strategy for electrocatalytic production of a liquid organic hydrogen carrier with anodic valorization of the process. This review summarizes the state of the art and outlooks in this new concept. The electrocatalytic process is briefly introduced, and the main components are discussed. Subsequently, the electrocatalytic production of liquid organic hydrogen carriers and anodic oxidation from components to processes, together with the paired processes and reactors, are analyzed, highlighting challenges and prospects.