One- and two-electron reduction of molybdate reversibly bound to the archaeal tungstate/molybdate transporter WtpA
Journal Article
(2009)
Research Group
BT/Biocatalysis
DOI related publication
https://doi.org/10.1039/b914697k
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Publication Year
2009
Language
English
Research Group
BT/Biocatalysis
Issue number
39
Pages (from-to)
8168-8170
Abstract
Reversible binding of the tetrahedral oxoanions MoO4 2- and WO4 2- to two carboxylato ligands of the soluble scavenger protein WtpA from the hyperthermophilic archaeon Pyrococcus furiosus enforces a quasi-octahedral MO6 coordination in which the +VI oxidation state is destabilized.
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