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A Photochemoenzymatic Hunsdiecker-Borodin-Type Halodecarboxylation of Ferulic Acid

Journal Article (2022)
Author(s)

Claudio Zippilli (Universita degli Studi della Tuscia Viterbo, TU Delft - Applied Sciences)

Miguel Jimenez Bartolome (University of Natural Resources and Applied Life Sciences)

Thomas Hilberath (TU Delft - Applied Sciences)

Lorenzo Botta (Universita degli Studi della Tuscia Viterbo)

Frank Hollmann (TU Delft - Applied Sciences)

Raffaele Saladino (Universita degli Studi della Tuscia Viterbo)

Research Group
BT/Biocatalysis
DOI related publication
https://doi.org/10.1002/cbic.202200367 Final published version
More Info
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Publication Year
2022
Language
English
Research Group
BT/Biocatalysis
Journal title
ChemBioChem
Issue number
19
Volume number
23
Article number
e202200367
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Abstract

A photochemoenzymatic halodecarboxylation of ferulic acid was achieved using vanadate-dependent chloroperoxidase as (bio)catalyst and oxygen and organic solvent as sole stoichiometric reagents in a biphasic system. Performance and selectivity were improved through a phase transfer catalyst, reaching a turnover number of 660.000 for the enzyme.