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Natural Deep Eutectic Solvents as Performance Additives for Peroxygenase Catalysis

Journal Article (2019)
Author(s)

Yunjian Ma (South China University of Technology)

Yongru Li (South China University of Technology)

Shahid Ali (South China University of Technology)

Peilin Li (South China University of Technology)

W. Zhang (TU Delft - BT/Biocatalysis)

M.C.R. Rauch (TU Delft - BT/Biocatalysis)

Sébastien Willot (TU Delft - BT/Biocatalysis)

Doris Ribitsch (acib GmbH)

F. Hollmann (TU Delft - BT/Biocatalysis)

More Authors (External organisation)

Research Group
BT/Biocatalysis
Copyright
© 2019 Yunjian Ma, Yongru Li, Shahid Ali, Peilin Li, W. Zhang, M.C.R. Rauch, S.J. Willot, Doris Ribitsch, F. Hollmann, More Authors
DOI related publication
https://doi.org/10.1002/cctc.201901842
More Info
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Publication Year
2019
Language
English
Copyright
© 2019 Yunjian Ma, Yongru Li, Shahid Ali, Peilin Li, W. Zhang, M.C.R. Rauch, S.J. Willot, Doris Ribitsch, F. Hollmann, More Authors
Research Group
BT/Biocatalysis
Issue number
4
Volume number
12
Pages (from-to)
989-994
Reuse Rights

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Abstract

Natural deep eutectic solvents (NADES) are proposed as alternative solvents for peroxygenase-catalysed oxyfunctionalization reactions. Choline chloride-based NADES are of particular interest as they can serve as solvent, enzyme-stabiliser and sacrificial electron donor for the in situ H2O2 generation. This report provides the first proof-of-concept and basic characterisation of this new reaction system. Highly promising turnover numbers for the biocatalysts of up to 200,000 have been achieved.