Marine Rauch
15 records found
1
Authored
Cofactors assist enzymes to catalyze reactions and are indispensable and ubiquitous in nature, playing a central role in metabolic pathways. In biocatalysis, common redox cofactors such as nicotinamide, flavin and heme can be activated by light or synthetized to vary redox pot ...
Direct, NAD(P)H-independent regeneration of Old Yellow Enzymes represents an interesting approach for simplified reaction schemes for the stereoselective reduction of conjugated C=C-double bonds. Simply by illuminating the reaction mixtures with blue light in the presence of s ...
Metals in Biotechnology
Cr-Driven Stereoselective Reduction of Conjugated C=C Double Bonds
Formate Oxidase (FOx) from Aspergillus oryzae
One Catalyst Enables Diverse H 2 O 2 -Dependent Biocatalytic Oxidation Reactions
An increasing number of biocatalytic oxidation reactions rely on H 2 O ...
Biocatalytic oxyfunctionalisation reactions are traditionally conducted in aqueous media limiting their production yield. Here we report the application of a peroxygenase in neat reaction conditions reaching product concentrations of up to 360 mM.
@enDeazaflavins are potentially useful redox mediators for the direct, nicotinamide-independent regeneration of oxidoreductases. Especially the O2-stability of their reduced forms have attracted significant interest for the regeneration of monooxygenases. In this contr ...