Peroxygenase-Catalysed Epoxidation of Styrene Derivatives in Neat Reaction Media
Marine C.R. Rauch (TU Delft - BT/Biocatalysis)
Florian Tieves (TU Delft - BT/Biocatalysis)
C.E. Paul (TU Delft - BT/Biocatalysis)
I.W.C.E. Arends (Universiteit Utrecht)
Miguel Alcalde (Institute of Catalysis, CSIC, Madrid)
Frank Hollmann (TU Delft - BT/Biocatalysis)
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Abstract
Biocatalytic oxyfunctionalisation reactions are traditionally conducted in aqueous media limiting their production yield. Here we report the application of a peroxygenase in neat reaction conditions reaching product concentrations of up to 360 mM.