The Effect of Salts on the CO2 Reduction Product Distribution in an Aprotic Electrolyte
I.A.E. Burgers (TU Delft - Large Scale Energy Storage)
Boris Wortmann (Student TU Delft)
Amanda Cristina Garcia (Universiteit van Amsterdam)
Connor Deacon-Price (Universiteit van Amsterdam)
Elena Pérez-Gallent (TNO)
Earl Goetheer (TU Delft - Energy Technology)
R. Kortlever (TU Delft - Large Scale Energy Storage)
More Info
expand_more
Other than for strictly personal use, it is not permitted to download, forward or distribute the text or part of it, without the consent of the author(s) and/or copyright holder(s), unless the work is under an open content license such as Creative Commons.
Abstract
Electrochemical CO2 reduction in non-aqueous solvents is promising due to the increased CO2 solubility of organic-based electrolytes compared to aqueous electrolytes. Here the effect of nine different salts in propylene carbonate (PC) on the CO2 reduction product distribution of polycrystalline Cu is investigated. Three different cations (tetraethylammonium (TEA), tetrabutylammonium (TBA), and tetrahexylammonium (THA)) and three different anions (chloride (Cl), tetrafluoroborate (BF4), and hexafluorophosphate (PF6)) were used. Chronoamperometry and in-situ FTIR measurements show that the size of the cation has a crucial role in the selectivity. A more hydrophobic surface is obtained when employing a larger cation with a weaker hydration shell. This stabilizes the CO2− radical and promotes the formation of ethylene. CO2 reduction in 0.7 M THACl/PC shows the highest hydrocarbon formation. Lastly, we hypothesize that the hydrocarbon formation pathway is not through C−C coupling, as the CO solubility in PC is very high, but through the dimerization of the COH intermediate.
help_outline