Advancing integrated CO₂ electrochemical conversion with amine-based CO₂ capture

Abstract

Carbon dioxide (CO₂) electrolysis is a promising route to utilise captured CO₂ as a building block to produce valuable feedstocks and fuels such as carbon monoxide and ethylene. Very recently, CO₂ electrolysis has been proposed as an alternative process to replace the amine recovery unit of the commercially available amine-based CO₂ capture process. This process would replace the most energy-intensive unit operation in amine scrubbing while providing a route for CO₂ conversion. The key enabler for such process integration is to develop an efficient integrated electrolyser that can convert CO₂ and recover the amine simultaneously. Herein, this review provides an overview of the fundamentals and recent progress in advancing integrated CO₂ conversion in amine-based capture media. This review first discusses the mechanisms for both CO₂ absorption in the capture medium and electrochemical conversion of the absorbed CO₂. We then summarise recent advances in improving the efficiency of integrated electrolysis via innovating electrodes, tailoring the local reaction environment, optimising operation conditions (e.g., temperatures and pressures), and modifying cell configurations. This review is concluded with future research directions for understanding and developing integrated CO₂ electrolysers.