Polymers of Intrinsic Microporosity as High Temperature Templates for the Formation of Nanofibrous Oxides
Journal Article
(2015)
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© 2015 RSC
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https://doi.org/doi:10.1039/C5RA15131G
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Publication Year
2015
Copyright
© 2015 RSC
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Abstract
The highly rigid molecular structure of Polymers of Intrinsic Microporosity (PIM) – associated with a high thermolysis threshold – combined with the possibility to fill intrinsic micropores allows the direct “one-step” templated conversion of metal nitrates into nano-structured metal oxides. This is demonstrated here with PIM-EA-TB and with PIM-1 for the conversion of Pr(NO3)3 to Pr6O11.