Substitution Pattern Controlled Quantum Interference in [2.2]Paracyclophane-Based Single-Molecule Junctions
C. Hsu (TU Delft - QN/van der Zant Lab, Kavli institute of nanoscience Delft)
Ksenia Reznikova (University of Basel)
Werner M. Schosser (Universität Augsburg)
Almudena Gallego (University of Basel)
Katawoura Beltako (Universität Augsburg)
Fabian Pauly (Universität Augsburg)
H.S.J. van der Zant (TU Delft - QN/van der Zant Lab, Kavli institute of nanoscience Delft)
Marcel Mayor (University of Basel)
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Abstract
Quantum interference (QI) within a single-molecule junction has become an essential yet powerful concept to integrate for designing molecular electronic devices.1 Recently we have investigated the correlation between substitution pattern, conductance and mechanosensitivity in [2.2]paracyclophane(PCP)-based single-molecule junction via the mechanically controlled break junction technique (MCBJ).2,3 We study the influence on conductance when we introduce meta/para connection to the PCP core and the phenyl ring attached to the anchoring group. We find that (i) meta-phenyl-anchored PCP yields such low conductance levels that molecular features cannot be resolved; (ii) para-phenyl-coupled anchoring generally gives higher conductance levels which can be detected via MCBJ; (iii) pseudo-para-coupled PCP core manifests large mechanosensitivity while (iv) pseudo-meta-coupled PCP core show the absence of mechanosensitivity. These experimental findings are interpreted in terms of QI effects between molecular frontier orbitals by theoretical calculations based on density functional theory and the Landauer formalism.
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