The properties of pulsed laser deposited YH2 films for switchable devices

Abstract

In-situ deposited YH2 films ranging from epitaxial to nanocrystalline were prepared by pulsed laser deposition (PLD). PLD has the advantage that the yttrium target acts as a hydrogen source. Comparing the switching behavior to that of MBE-grown, ex-situ loaded films, the PLD-films show a reduced optical and electrical contrast in switching, which is probably due to the formation of Y(OH)3. On the other hand, we found that in the nanocrystalline PLD-films the hysteresis in switching is absent. Moreover, these films have a smoother surface morphology. Both effects are important for the implementation of switchable rare earth hydride films in all-solid-state devices.