Title
Process Integration of Electrolysis, Gasification and Syngas Upgrading for Biofuel Production: A techno-economic assessment
Author
Milisav, Andrej (TU Delft Electrical Engineering, Mathematics and Computer Science)
Contributor
de Jong, W. (mentor) 
Ramdin, M. (mentor)
Degree granting institution
Delft University of Technology
Programme
Electrical Engineering | Sustainable Energy Technology
Date
2023-05-22
Abstract
The transport sector remains one of the largest CO2 emitting sectors globally. Decarbonizing the transport sector is an important aspect in the energy transition. The word transition is key, since it will take several decades or more to transition to a fully sustainable world. During this transition mainly heavy-duty vehicles and probably most vehicles in third world countries will rely on liquid transportation fuels. Affordable and competitive biofuels are the way to fill this need in a sustainable way.
This study will focus on integrating several sustainable units and feedstocks to produce gasoline and diesel, starting with a pyrolysis oil feedstock. The integrated units consist of a gasifier, whose gasifying agent, oxygen, is produced by a SOEC electrolyser, running on renewable electricity. The syngas produced in the gasifier is produced during a low temperature Fischer Tropsch process over a cobalt catalyst. The aim is to choose operating conditions resulting in a large chain growth probability factor to produce heavier hydrocarbons chains, which can be refined to mainly yield diesel. The hydrogen required to upgrade the syngas formed in the gasifier is supplied by the SOEC electrolyser as well. The final upgrading of the produced crude oil is performed by separating the fractions in distillation columns and using a hydrocracker to raise the yield of the desired products. The end products are diesel and gasoline, meant to be blended in with gasoline and diesel from conventional oil refineries. The gasoline and diesel are sulfur free and especially the diesel is of high quality, due to tuning the process to predominantly produce paraffinic hydrocarbons.
The assessment of the process will be a techno-economic analysis based on a model made with Aspen plus. 5000 kg·hr-1 of bio-oil produced by BTG was converted to 990 kg·hr-1 of high-quality diesel and 557 kg·hr-1 of gasoline. The overall carbon conversion of the process to the end products was 57.6 %. By designing a heat exchanger network, optimizing the energy produced and needed by the heat sources and sinks respectively, an overall energy efficiency on LHV base of 57.2 % was reached. The process in the current day and age was found to not be profitable yet, but will definitely be in the future.
Subject
Fischer Tropsch
biomass to liquid
process integration
sustainable
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http://resolver.tudelft.nl/uuid:4d2cdda8-f311-4275-85a8-1443ab6c8cc9
Embargo date
2025-05-22
Part of collection
Student theses
Document type
master thesis
Rights
© 2023 Andrej Milisav