Slow Shallow Energy States as the Origin of Hysteresis in Perovskite Solar Cells

Slow Shallow Energy States as the Origin of Hysteresis in Perovskite Solar Cells

van Heerden, Rik (Student TU Delft)
Procel Moya, P.A. (TU Delft Photovoltaic Materials and Devices; Universidad San Francisco de Quito)
Mazzarella, L. (TU Delft Photovoltaic Materials and Devices)
Santbergen, R. (TU Delft Photovoltaic Materials and Devices)
Isabella, O. (TU Delft Photovoltaic Materials and Devices)

2022

Organic-inorganic metal halide perovskites have attracted a considerable interest in the photovoltaic scientific community demonstrating a rapid and unprecedented increase in conversion efficiency in the last decade. Besides the stunning progress in performance, the understanding of the physical mechanisms and limitations that govern perovskite solar cells are far to be completely unravelled. In this work, we study the origin of their hysteretic behaviour from the standpoint of fundamental semiconductor physics by means of technology computer aided design electrical simulations. Our findings identify that the density of shallow interface defects at the interfaces between perovskite and transport layers plays a key role in hysteresis phenomena. Then, by comparing the defect distributions in both spatial and energetic domains for different bias conditions and using fundamental semiconductor equations, we can identify the driving force of hysteresis in terms of slow recombination processes and charge distributions.

TCAD senaturus
hysteresis
perovskite solar cell device simulation
defect states simulations
defect distribution model

http://resolver.tudelft.nl/uuid:b6bfb581-d217-46f4-b073-04729dc51116

https://doi.org/10.3389/fphot.2022.889837

2673-6853

Frontiers in Photonics, 3

Institutional Repository

journal article

© 2022 Rik van Heerden, P.A. Procel Moya, L. Mazzarella, R. Santbergen, O. Isabella