Print Email Facebook Twitter A Photochemoenzymatic Hunsdiecker-Borodin-Type Halodecarboxylation of Ferulic Acid Title A Photochemoenzymatic Hunsdiecker-Borodin-Type Halodecarboxylation of Ferulic Acid Author Zippilli, C. (TU Delft BT/Biocatalysis; Universita degli Studi della Tuscia Viterbo) Bartolome, Miguel Jimenez (Universityof NaturalResourcesand Life Sciences, Vienna) Hilberath, T. (TU Delft BT/Biocatalysis) Botta, Lorenzo (Universita degli Studi della Tuscia Viterbo) Hollmann, F. (TU Delft BT/Biocatalysis) Saladino, Raffaele (Universita degli Studi della Tuscia Viterbo) Date 2022 Abstract A photochemoenzymatic halodecarboxylation of ferulic acid was achieved using vanadate-dependent chloroperoxidase as (bio)catalyst and oxygen and organic solvent as sole stoichiometric reagents in a biphasic system. Performance and selectivity were improved through a phase transfer catalyst, reaching a turnover number of 660.000 for the enzyme. Subject halodecarboxylationphase-transfer catalysisphotobiocatalysisphotochemoenzymatic reactionsvanadium chloroperoxidase To reference this document use: http://resolver.tudelft.nl/uuid:3ca35482-f0a2-45b6-8f72-8974ba8b7904 DOI https://doi.org/10.1002/cbic.202200367 ISSN 1439-4227 Source ChemBioChem: a European journal of chemical biology, 23 (19) Part of collection Institutional Repository Document type journal article Rights © 2022 C. Zippilli, Miguel Jimenez Bartolome, T. Hilberath, Lorenzo Botta, F. Hollmann, Raffaele Saladino Files PDF ChemBioChem_2022_Zippilli ... c_Acid.pdf 940.4 KB Close viewer /islandora/object/uuid:3ca35482-f0a2-45b6-8f72-8974ba8b7904/datastream/OBJ/view