Print Email Facebook Twitter Expanding the Spectrum of Light-Driven Peroxygenase Reactions Title Expanding the Spectrum of Light-Driven Peroxygenase Reactions Author Willot, S.J. (TU Delft BT/Biocatalysis) Fernandez Fueyo, E. (TU Delft BT/Biocatalysis; TU Delft BN/Greg Bokinsky Lab) Tieves, F. (TU Delft BT/Biocatalysis) Pesic, M. (TU Delft BT/Biocatalysis) Alcalde, Miguel (Institute of Catalysis, CSIC, Madrid) Arends, I.W.C.E. (Universiteit Utrecht) Park, Chan Beum (Korea Advanced Institute of Science and Technology) Hollmann, F. (TU Delft BT/Biocatalysis) Date 2019 Abstract Peroxygenases require a controlled supply of H2O2 to operate efficiently. Here, we propose a photocatalytic system for the reductive activation of ambient O2 to produce H2O2 which uses the energy provided by visible light more efficiently based on the combination of wavelength-complementary photosensitizers. This approach was coupled to an enzymatic system to make formate available as a sacrificial electron donor. The scope and current limitations of this approach are reported and discussed. Subject biocatalysisformate dehydrogenasehydrogen peroxide formationoxyfunctionalizationperoxygenasesphotocatalysis To reference this document use: http://resolver.tudelft.nl/uuid:4e2e5186-02a1-4888-a031-b03efbacc454 DOI https://doi.org/10.1021/acscatal.8b03752 ISSN 2155-5435 Source ACS Catalysis, 9 (2), 890-894 Part of collection Institutional Repository Document type journal article Rights © 2019 S.J. Willot, E. Fernandez Fueyo, F. Tieves, M. Pesic, Miguel Alcalde, I.W.C.E. Arends, Chan Beum Park, F. Hollmann Files PDF acscatal.8b03752.pdf 1.34 MB Close viewer /islandora/object/uuid:4e2e5186-02a1-4888-a031-b03efbacc454/datastream/OBJ/view