Print Email Facebook Twitter Hidden Figures of Photo-charging Title Hidden Figures of Photo-charging: a thermo-electrochemical approach for a solar-rechargeable redox flow cell system Author Bae, D. (TU Delft ChemE/Materials for Energy Conversion and Storage) Faasse, Richard (Student TU Delft) Smith, W.A. (TU Delft ChemE/Materials for Energy Conversion and Storage; National Renewable Energy Laboratory; University of Colorado) Date 2020 Abstract Achieving high current densities without thermal performance degradation at high temperatures is one of the main challenges for enhancing the competitiveness of photo-electrochemical energy storage systems. We describe a system that overcomes this challenge by incorporating an integrated photoelectrode with a redox flow cell, which functions as a coolant for the excess heat from the photo-absorber. We perform quantitative analyses to theoretically validate and highlight the merit of the system. Practical operation parameters, including daily temperature and redox reaction kinetics, are modeled with respect to heat and charge transfer mechanisms. Our analyses show a profound impact on the resulting solar-to-chemical efficiencies and stored power, which are 21.8% higher than that of a conventional photovoltaic-assisted energy storage system. This paves the way for reassessing the merit of photovoltaic-integrated systems, which have hitherto been underrated as renewable energy storage systems. Subject Redox flow batteryPhotoelectrochemical cellsphotoelectrochemistryEnergy storageThermal degradationModelingEnergy conversionRenewable energy To reference this document use: http://resolver.tudelft.nl/uuid:86321ef8-7760-42b9-ab80-4d11190ab1cf DOI https://doi.org/10.1039/d0se00348d ISSN 2398-4902 Source Sustainable Energy & Fuels, 4 (6), 2650-2655 Part of collection Institutional Repository Document type journal article Rights © 2020 D. Bae, Richard Faasse, W.A. Smith Files PDF D0SE00348D_Final_version.pdf 668.29 KB PDF SEF_communication_SI_resu ... et_al..pdf 979.07 KB Close viewer /islandora/object/uuid:86321ef8-7760-42b9-ab80-4d11190ab1cf/datastream/OBJ1/view