A solvent-free synthesis of (thio)ester derivatives using FeCl&lt;sub&gt;3&lt;/sub&gt; as a heterogeneous catalyst

Younes, S.H.H.; Hollmann, F.

doi:10.1016/j.tetlet.2023.154524

A solvent-free synthesis of (thio)ester derivatives using FeCl₃ as a heterogeneous catalyst

Title

A solvent-free synthesis of (thio)ester derivatives using FeCl₃ as a heterogeneous catalyst

Author

Younes, S.H.H. (TU Delft BT/Biocatalysis; Sohag University)
Hollmann, F. (TU Delft BT/Biocatalysis)

Date

2023

Abstract

A simple, solvent-free method for the synthesis of (thio)esters from simple acid chlorides at room temperature is reported. Simple FeCl₃ (5 mol%) enables facile, near complete conversion of equimolar starting materials in high selectivity. Recycling of the catalyst has been demonstrated.

Subject

FeCl
Thioester

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http://resolver.tudelft.nl/uuid:8cadfff8-c861-466b-bbc6-571d3502187a

DOI

https://doi.org/10.1016/j.tetlet.2023.154524

ISSN

0040-4039

Source

Tetrahedron Letters, 123

Part of collection

Institutional Repository