Print Email Facebook Twitter Thermodynamic Description of the ACl-ThCl4 (A = Li, Na, K) Systems Title Thermodynamic Description of the ACl-ThCl4 (A = Li, Na, K) Systems Author Ocadiz flores, J.A. (TU Delft RST/Reactor Physics and Nuclear Materials) Rooijakkers, B.A.S. (Student TU Delft) Konings, R. (TU Delft RST/Reactor Physics and Nuclear Materials; European Commission, Karlsruhe) Smith, A.L. (TU Delft RST/Reactor Physics and Nuclear Materials) Date 2021 Abstract The ACl-ThCl (Formula presented.) (A = Li, Na, K) systems could be of relevance to the nuclear industry in the near future. A thermodynamic investigation of the three binary systems is presented herein. The excess Gibbs energy of the liquid solutions is described using the quasi-chemical formalism in the quadruplet approximation. The phase diagram optimisations are based on the experimental data available in the literature. The thermodynamic stability of the liquid solutions increases in the order Li < Na < K, in agreement with idealised interactions and structural models. To reference this document use: http://resolver.tudelft.nl/uuid:a53e471e-a72a-45a0-a796-959ebeadf4a1 DOI https://doi.org/10.3390/thermo1020009 ISSN 2673-7264 Source Thermo, 1 (2), 122-133 Part of collection Institutional Repository Document type journal article Rights © 2021 J.A. Ocadiz flores, B.A.S. Rooijakkers, R. Konings, A.L. Smith Files PDF thermo_01_00009_v2.pdf 489.79 KB Close viewer /islandora/object/uuid:a53e471e-a72a-45a0-a796-959ebeadf4a1/datastream/OBJ/view