Print Email Facebook Twitter Zinc Composite Layers, Incorporating Polymeric Nano-aggregates: Surface Analysis and Electrochemical Behavior Title Zinc Composite Layers, Incorporating Polymeric Nano-aggregates: Surface Analysis and Electrochemical Behavior Author Koleva, D.A. Zhang, X. Petrov, P. Boshkov, N. Van Breugel, K. De Wit, J.H.W. Mol, J.M.C. Tsvetkova, N. Faculty Delft University of Technology Date 2008-12-31 Abstract This study reports on a comparative investigation of the corrosion behavior of zinc (Zn) and nano-composite zinc (ZnC) galvanic layers in 5% NaCl solution. The metallic matrix of the ZnC layers incorporates nano-sized, stabilized polymeric aggregates, formed from the amphiphilic tri-block co-polymer: poly(2-hydroxyethyl methacrylate) - poly (propylene oxide - poly (2-hydroxyethyl methacrylate) (PHEMA15PPO34PHEMA15). The main objective was to evaluate the electrochemical properties and surface characteristics of both coatings, thus further to investigate if the nano-composite layers will have better corrosion resistance, compared to pure galvanic zinc. The electrochemical behavior, investigated by Impedance spectroscopy (EIS) and Scanning vibrating electrode technique (SVET), supported by surface analysis, using Atomic-force microscopy (AFM) and Scanning electron microscopy (SEM), reveals higher corrosion resistance and consequently better performance of the nano-composite layers, compared to pure galvanic zinc. The mechanism of incorporation of the polymeric nano-aggregates in the coating and their influence on the barrier properties of the composite layers are also briefly discussed. To reference this document use: http://resolver.tudelft.nl/uuid:ae46fa9c-adf8-4e7f-8a4d-15ccee910116 DOI https://doi.org/10.1149/1.2889405 Publisher The Electrochemical Society ISSN 1938-5862 Source ECS Transaction, 11 (11), 2008 Part of collection Institutional Repository Document type journal article Rights © 2008 The Electrochemical Society Files PDF Koleva_2008.pdf 353.63 KB Close viewer /islandora/object/uuid:ae46fa9c-adf8-4e7f-8a4d-15ccee910116/datastream/OBJ/view