Geometric Catalyst Utilization in Zero-Gap CO₂Electrolyzers

The electrochemical reduction of CO2 (CO2RR) on silver catalysts has been demonstrated under elevated current density, longer reaction times, and intermittent operation. Maintaining performance requires that CO2 can access the entire geometric catalyst area, thus maximizing catalyst utilization. Here we probe the time-dependent factors...

Advancing integrated CO₂ electrochemical conversion with amine-based CO₂ capture: a review

Carbon dioxide (CO₂) electrolysis is a promising route to utilise captured CO₂ as a building block to produce valuable feedstocks and fuels such as carbon monoxide and ethylene. Very recently, CO₂ electrolysis has been proposed as an alternative process to replace the amine recovery unit of the commercially...

Cation-Driven Increases of CO₂Utilization in a Bipolar Membrane Electrode Assembly for CO₂Electrolysis

Advancing reaction rates for electrochemical CO2 reduction in membrane electrode assemblies (MEAs) have boosted the promise of the technology while exposing new shortcomings. Among these is the maximum utilization of CO2, which is capped at 50% (CO as targeted product) due to unwanted homogeneous reactions. Using bipolar membranes in an MEA ...