Synthesis, characterization and performance of bifunctional catalysts for the synthesis of menthol from citronellal

The synthesis of a series of bifunctional catalysts (1 wt% Pt/W-TUD-1 (Technische Universiteit Delft-1) and 1 wt% Pt/WO₃/TUD-1) with different tungsten loadings (5-30 wt% WO₃) is described. They were characterized using ICP-OES, INAA, N₂ physisorption, XRD and TEM. Their catalytic performance (activity and...

B-TUD-1: A versatile mesoporous catalyst

Novel amorphous mesoporous borosilicate, B-TUD-1, was prepared to test its performance for different sustainable reactions. The structure of the material, the effective incorporation of boron into the framework as well as the nature of incorporated boron were verified by N2-sorption, XRD, ICP-OES, TEM, NH3-desorption, MAS NMR and FTIR. The...

Pt/Al2O3 Catalyzed 1,3-Propanediol Formation from Glycerol using Tungsten Additives

Screening of four commercial catalysts (Pt/Al2O3, Pt/SiO2, Pd/Al2O3, and Pd/SiO2) and four acidic additives (hydrochloric, tungstic, phosphotungstic, and silicotungstic acids) shows that the combination of a platinum hydrogenation catalyst with tungsten containing acidic additives yields 1,3-propanediol from aqueous glycerol. The performance of...